Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry.
comunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1021/ed100952d |
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Title
Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry.Date
2011-03Publisher
© 2011 The American Chemical Society and Division of Chemical EducationISSN
0021-9584Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/abs/10.1021/ed100952dSubject
Abstract
The preparation and characterization of two air-stable Rh(I) complexes bearing a chelating N-heterocyclic carbene (NHC) ligand is described. The synthesis involves the preparation of a Ag(I)-NHC complex and its use ... [+]
The preparation and characterization of two air-stable Rh(I) complexes bearing a chelating N-heterocyclic carbene (NHC) ligand is described. The synthesis involves the preparation of a Ag(I)-NHC complex and its use as carbene transfer agent to a Rh(I) precursor. The so obtained complex can be further reacted with carbon monoxide to give the corresponding carbonyl derivative. The students will be able to identify the products using standard characterization techniques such as NMR and IR spectroscopy. The required equipment is typically available in most of the standard laboratories for undergraduate students. (Contains 2 figures and 3 schemes.) [-]
Is part of
Journal of Chemical Education (March 2011), vol. 88, no. 6, 822–824Rights
http://rightsstatements.org/vocab/CNE/1.0/
info:eu-repo/semantics/restrictedAccess
info:eu-repo/semantics/restrictedAccess
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- QUIO_Articles [702]