Double CH bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenes
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Otros documentos de la autoría: Prades Ferrer, Amparo; Poyatos, Macarena; Mata Martínez, Jose A; Peris, Eduardo
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http://dx.doi.org/10.1002/anie.201101806 |
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Título
Double CH bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenesFecha de publicación
2011-06-29Editor
WileyCita bibliográfica
Angewandte Chemie International Edition (Aug. 2011), Volume 50, Issue 33, pages 7666–7669Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://onlinelibrary.wiley.com/doi/10.1002/anie.201101806/abstractPalabras clave / Materias
Resumen
Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double CH activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction ... [+]
Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double CH activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction constitutes a valuable approach to new carbene ligands with unprecedented architectures. [-]
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