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Stereoselective synthesis of the cytotoxic macrolide aspergillide B
dc.contributor.author | Diaz-Oltra, Santiago | |
dc.contributor.author | Angulo-Pachón, César A. | |
dc.contributor.author | Kneeteman, María N. | |
dc.contributor.author | Murga, Juan | |
dc.contributor.author | Carda, Miguel | |
dc.contributor.author | Marco, J. Alberto | |
dc.date.accessioned | 2012-08-07T09:55:53Z | |
dc.date.available | 2012-08-07T09:55:53Z | |
dc.date.issued | 2009 | |
dc.identifier | http://dx.doi.org/10.1016/j.tetlet.2009.04.026 | |
dc.identifier.citation | Tetrahedron Letters, 50, 27, p. 3783-3785 | |
dc.identifier.issn | 404039 | |
dc.identifier.uri | http://hdl.handle.net/10234/43710 | |
dc.description.abstract | A total, stereoselective synthesis of the cytotoxic macrolide aspergillide B has been performed. A cross metathesis and a C-glycosidation via a Mukaiyama-type aldol reaction were key features of the synthesis. The macrocyclic lactone ring was created by means of the Yamaguchi procedure. © 2009 Elsevier Ltd. All rights reserved. | |
dc.language.iso | eng | |
dc.publisher | Elsevier | |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.subject | Aspergillides | |
dc.subject | Brown asymmetric allylation | |
dc.subject | Cross metathesis | |
dc.subject | Macrolides | |
dc.subject | Mukaiyama C-glycosidation | |
dc.subject | Yamaguchi macrolactonization | |
dc.title | Stereoselective synthesis of the cytotoxic macrolide aspergillide B | |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | http://dx.doi.org/10.1016/j.tetlet.2009.04.026 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess |
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