Convergent, stereoselective syntheses of the glycosidase inhibitors broussonetines C, O and P
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Altres documents de l'autoria: Ribés Vidal, Celia; Falomir, Eva; Murga, Juan; Carda, Miguel; Marco, J. Alberto
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http://dx.doi.org/10.1016/j.tet.2009.10.066 |
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Títol
Convergent, stereoselective syntheses of the glycosidase inhibitors broussonetines C, O and PData de publicació
2009Editor
ElsevierISSN
404020Cita bibliogràfica
Tetrahedron, 65, 51, p. 10612-10616Tipus de document
info:eu-repo/semantics/articleResum
The first syntheses of the polyhydroxylated alkaloids (iminosugars) broussonetines O and P, glycosidase inhibitors of the pyrrolidine class, have been performed in a convergent, stereocontrolled way from d-serine as ... [+]
The first syntheses of the polyhydroxylated alkaloids (iminosugars) broussonetines O and P, glycosidase inhibitors of the pyrrolidine class, have been performed in a convergent, stereocontrolled way from d-serine as the chiral starting material. The synthesis of broussonetin C, a further member of this compound family, is also reported. A cross-metathesis step was one key feature of the synthesis. The versatility of the synthetic concept chosen permits the access to many members of this compound family, both natural ones and analogues thereof. © 2009 Elsevier Ltd. All rights reserved. [-]
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