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Counterbalance between Surface and Confinement Effects As Studied for Amino-Terminated Poly(propylene glycol) Constraint in Silica Nanopores
Kiprop Kipnusu, Wycliffe; M. Elmahdy, Mahdy; Elsayed, Mohamed; Krause-Rehberg, Reinhard; Kremer, Friedrich American Chemical Society (2019)Broadband dielectric spectroscopy (BDS) and orthopositronium annihilation lifetime spectroscopy (PALS) are combined to study the molecular dynamics and the free volume of poly(propylene glycol) terminated with amino end ...