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Triplication of the photocurrent in dye solar cells by increasing the elongation of the π-conjugation in Zn-porphyrin sensitizers
dc.contributor.author | Barea, Eva M | |
dc.contributor.author | Caballero, Rubén | |
dc.contributor.author | López Arroyo, Leticia | |
dc.contributor.author | De la Cruz, Pilar | |
dc.contributor.author | Langa, Fernando | |
dc.contributor.author | Bisquert, Juan | |
dc.contributor.author | Guerrero, Antonio | |
dc.date.accessioned | 2012-05-31T07:16:30Z | |
dc.date.available | 2012-05-31T07:16:30Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | ChemPhysChem (2011) vol. 12, no. 5, pp. 961-965 | ca_CA |
dc.identifier.issn | 1439-4235 | |
dc.identifier.issn | 1439-7641 | |
dc.identifier.uri | http://hdl.handle.net/10234/39400 | |
dc.description.abstract | Porphyrins are promising sensitizers for dye solar cells (DSCs) but narrow absorption bands at 400-450 and 500-650 nm limit their light-harvesting properties. Increasing elongation of the π-conjugation and loss of symmetry causes broadening and a red-shift of the absorption bands, which considerably improves the performance of the DSC. Herein we use an oligothienylenevinylene to bridge a Zn-porphyrin system and the anchoring group of the sensitizer. We separately study the performance of the two basic units: oligothienylenevinylene and Zn-porphyrin. The combined system provides a three-fold enhancement of the photocurrent with respect to parent dyes. This is caused by an additional strong absorption in the region 400-650 nm that leads to flat IPCE of 60%. Theoretical calculations support that the addition of the oligothienylenevinylene unit as a linking bridge creates a charge transfer band that transforms a Zn-porphyrin dye into a push-pull type system with highly efficient charge injection properties | ca_CA |
dc.format.extent | 15 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley-VCH Verlag Berlin | ca_CA |
dc.relation.isFormatOf | Versió pre-print del document publicat a: http://www.elp.uji.es/recursos/paper109.pdf | ca_CA |
dc.rights | © Wiley-VCH Verlag Berlin | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Dye solar cells | ca_CA |
dc.subject | Zn-porphyrin sensitizers | ca_CA |
dc.subject.lcsh | Solar cells | ca_CA |
dc.subject.other | Cèl·lules solars | ca_CA |
dc.title | Triplication of the photocurrent in dye solar cells by increasing the elongation of the π-conjugation in Zn-porphyrin sensitizers | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/cphc.201000958 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/submittedVersion |
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