Cp*Ir(NHC) complexes as highly versatile and efficient catalysts for the cross-coupling of alcohols and amines
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Title
Cp*Ir(NHC) complexes as highly versatile and efficient catalysts for the cross-coupling of alcohols and aminesDate
2008-11-19Publisher
Wiley-VCHISSN
0947-6539Bibliographic citation
PRADES FERRER, Amparo, et al. Cp* Ir (NHC) complexes as highly versatile and efficient catalysts for the cross-coupling of alcohols and amines. Chemistry : a European journal, 2008, v. 14, n. 36, p. 11474 – 11479Type
info:eu-repo/semantics/articleSubject
Abstract
A comparative study on the catalytic activity of a series of Cp*Ir(NHC)Cl2
complexes in several C-O and C-N coupling processes implying hydrogen-borrowing
mechanisms has been performed. The compound Cp*Ir(InBu)Cl2 ... [+]
A comparative study on the catalytic activity of a series of Cp*Ir(NHC)Cl2
complexes in several C-O and C-N coupling processes implying hydrogen-borrowing
mechanisms has been performed. The compound Cp*Ir(InBu)Cl2 (InBu = 1,3-di-n-butylimidazolylidene) showed to be highly effective in the cross coupling reactions of
amines and alcohols, providing high yields in the production of unsymmetrical ethers
and N-alkylated amines. A remarkable feature is that the processes were carried out in
the absence of base, phosphine or any other external additive. A comparative study with
other well known catalysts, such as Shvo’s catalyst, is also reported [-]
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Chemistry : a European journal, 2008, v. 14, n. 36Rights
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