High-resolution 3D printable inks based on functional polymeric ionic liquids for applications in carbon dioxide valorization
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Metadatos
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comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadatos
Título
High-resolution 3D printable inks based on functional polymeric ionic liquids for applications in carbon dioxide valorizationAutoría
Fecha de publicación
2024-06-05Editor
ElsevierISSN
2214-7810; 2214-8604Cita bibliográfica
S. Marchetti, C. Tinajero, G. Palmara, E. García-Verdugo, I. Roppolo, M. Zanatta, V. Sans, High-resolution 3D printable inks based on functional polymeric ionic liquids for applications in carbon dioxide valorization. Addit. Manuf. 89 (2024) 104304. https://doi.org/10.1016/j.addma.2024.104304Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://www.sciencedirect.com/science/article/pii/S2214860424003506Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
This study investigates the use of epoxy-functionalized acrylate-based 3D printable ink for creating high-resolution functionalized devices, exploring the possibility to further functionalize those for chemical ... [+]
This study investigates the use of epoxy-functionalized acrylate-based 3D printable ink for creating high-resolution functionalized devices, exploring the possibility to further functionalize those for chemical engineering applications. In fact, the control of the epoxy-functionalized surface enables the formation of active surfaces, and this study employs supported Ionic Liquids with catalytic properties as a proof of concept. Ionic liquids (ILs) and polymeric derivatives represent a promising path to generate multifunctional complex 3D structures, playing advanced roles in multiple applications. The fine-tuning of the functionalization methodology and formulation enhances the resolution of acrylate-based resins, allowing the production of highly detailed structures that can significantly boost catalytic efficiency. Through a comparison with commercial resins, the developed formulation demonstrates superior resolution capabilities, positioning it as an effective alternative for use in vat photopolymerization technologies. Additionally, controlling the level of functionalization and accessibility of the ILs' active sites through the control of the surface area of the reactor has led to improved process performance in terms of yield and space-time yield (STY) in the CO2 cycloaddition to epoxide reaction. [-]
Publicado en
Additive Manufacturing, 2024, vol. 89Entidad financiadora
Ministerio de Ciencia, Innovación y Universidades | Ministerio de Ciencia e Innovación | Generalitat Valenciana | GenT | Santiago Grisolía Programme | European Union | La Caixa Foundation | FSE REACT-EU-PON Ricerca e Innovazione 2014-2020
Identificador de la entidad financiadora
http://dx.doi.org/10.13039/501100011033
Código del proyecto o subvención
MICIU/ICTI2017-2020/PID2020-119628RB-C33 | MCIN/PEICTI2021-2023/PID 2021-124695OB-C22 | TED2021-130288B-I00 | IDIFEDER/2021/029 | CIDEGENT 2018/036 | CIGRIS/2021/075 | info:eu-repo/grantAgreement/EC/H2020/101064606 | LCF/BQ/ PR24/12050016
Título del proyecto o subvención
Fabricación avanzada para procesos de cristalización de perovskitas | Nuevas herramientas en química verde para el desarrollo de procesos (bio)catalíticos sostenibles de valorización del CO2 y la obtención compuestos de alto valor añadido
Derechos de acceso
info:eu-repo/semantics/openAccess
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