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Gold(I) Complex with a Photoactive Ligand Behaves as a Two-in-One Dual Metallaphotoredox Cross-Coupling Catalyst
dc.contributor.author | Ruiz Zambrana, César Luís | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2024-05-31T06:31:28Z | |
dc.date.available | 2024-05-31T06:31:28Z | |
dc.date.issued | 2024-02-29 | |
dc.identifier.citation | César Ruiz-Zambrana, Macarena Poyatos, and Eduardo Peris. Gold(I) Complex with a Photoactive Ligand Behaves as a Two-in-One Dual Metallaphotoredox Cross-Coupling Catalyst. ACS Catalysis 2024 14 (6), 4066-4073 DOI: 10.1021/acscatal.3c05962 | ca_CA |
dc.identifier.issn | 2155-5435 | |
dc.identifier.uri | http://hdl.handle.net/10234/207561 | |
dc.description.abstract | We herein describe the use of a gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NDI-NHC) ligand, which was used as a photocatalyst for a variety of reactions. Due to the presence of the naphthalene moiety in the ligand, the complex can be used for the photogeneration of singlet oxygen, behaving as a photocatalyst in the endoperoxidation and peroxidation of cyclic and acyclic alkenes, and also in the selective oxidation of a simulant of sulfur mustard to its related nontoxic sulfoxide. The same complex was used as catalyst for two model oxidative C–C coupling reactions, namely, the coupling of aryldiazonium salts with alkynylsilanes and with mesitylene. These two catalytic reactions are a good indication that the (NDI-NHC)-Au(I) complex can behave as an effective dual metallophotoredox catalyst but with the particular feature that both the photosensitizer and the metal catalyst are contained in the same compound, thus constituting a very rare type of a “two-in-one” metallophotoredox catalyst. The participation of the Au(I)/Au(III) couple in the catalytic process was demonstrated by the isolation of a Au(III) complex, which was obtained via a self-photoactivated photoredox reaction. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 8 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation | NHCS inteligentes para la obtención de ensamblajes supramoleculares y catalizadores conmutables | ca_CA |
dc.relation.isPartOf | ACS Catalysis, 2024, vol. 14, no 6 | ca_CA |
dc.rights | Copyright © 2024 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0. | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | ca_CA |
dc.subject | gold | ca_CA |
dc.subject | metallaphotoredox | ca_CA |
dc.subject | two-in-one photocatalyst | ca_CA |
dc.subject | singlet oxygen | ca_CA |
dc.subject | endoperoxidation | ca_CA |
dc.subject | C–C coupling | ca_CA |
dc.subject | N-heterocyclic carbene | ca_CA |
dc.title | Gold(I) Complex with a Photoactive Ligand Behaves as a Two-in-One Dual Metallaphotoredox Cross-Coupling Catalyst | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1021/acscatal.3c05962 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.acs.org/doi/full/10.1021/acscatal.3c05962 | ca_CA |
dc.description.sponsorship | We gratefully acknowledge the financial support from the Ministerio de Ciencia y Universidades (PID2021-127862NB-I00), Generalitat Valenciana (CIPROM/2021/079), and the Universitat Jaume I (UJI-B2020-01 and UJI-B2021-39). We are grateful to the Serveis Centrals d’Instrumentació Científica (SCIC-UJI) for providing with spectroscopic facilities. | |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.identifier | http://dx.doi.org/10.13039/501100011033 | ca_CA |
project.funder.name | Ministerio de Ciencia e Innovación | ca_CA |
project.funder.name | Generalitat Valenciana | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
oaire.awardNumber | MCIN/PEICTI2021-2023/PID2021-127862NB-I00 | ca_CA |
oaire.awardNumber | CIPROM/2021/079 | ca_CA |
oaire.awardNumber | UJI-B2020-01 | ca_CA |
oaire.awardNumber | UJI-B2021-39 | ca_CA |
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