dc.contributor.author | Lima Patrocinio, Katiana | |
dc.contributor.author | Santos, Jeziel Rodrigues | |
dc.contributor.author | Granone, Luis Ignacio | |
dc.contributor.author | Ponce, Miguel Adolfo | |
dc.contributor.author | Churio, Maria Sandra | |
dc.contributor.author | Ribeiro, Lara Kelly | |
dc.contributor.author | Daldin Teodoro, Marcio | |
dc.contributor.author | Llusar, Rosa | |
dc.contributor.author | Andres, Juan | |
dc.contributor.author | Longo, Elson | |
dc.contributor.author | Assis, Marcelo de | |
dc.date.accessioned | 2023-10-30T11:22:00Z | |
dc.date.available | 2023-10-30T11:22:00Z | |
dc.date.issued | 2023-09-30 | |
dc.identifier.citation | PATROCINIO, Katiana Lima, et al. Tuning the morphology to enhance the catalytic activity of α-Ag 2 WO 4 through V-doping. Dalton Transactions, 2023. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/204697 | |
dc.description.abstract | Here, we present the synthesis of a highly efficient V-doped α-Ag2WO4 catalyst for the oxidation of sulfides to sulfones, exhibiting a high degree of tolerance towards various sensitive functional groups. Remarkably, the catalysts with 0.01% V-doping content exhibited outstanding selectivity towards the oxidation process. Scavenger experiments indicated the direct involvement of electron–hole (e−/h+) pairs, hydroxyl radical (˙OH), and singlet oxygen (1O2) in the catalytic mechanism. Based on the experimental and theoretical results, the higher activity of the V-doped α-Ag2WO4 samples was associated with the preferential formation of the (100) surface in the catalyst morphology. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 13 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.rights | This journal is © The Royal Society of Chemistry 2023 | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | ca_CA |
dc.subject | α-Ag2WO4 | ca_CA |
dc.subject | silver tungstate | ca_CA |
dc.subject | catalytic activity | ca_CA |
dc.subject | V-doping | ca_CA |
dc.title | Tuning the morphology to enhance the catalytic activity of α-Ag2WO4 through V-doping | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | 10.1039/D3DT02352D | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Fundaçao de Amparo à Pesquisa do Estado de São Paulo (FAPESP) | ca_CA |
project.funder.name | Financiadora de Estudos e Projetos – FINEP | ca_CA |
project.funder.name | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | ca_CA |
project.funder.name | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior – CAPES | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | Generalitat Valenciana | ca_CA |
project.funder.name | Margarita Salas postdoctoral contract MGS/2021/21 | ca_CA |
project.funder.name | European Union-Next Generation EU | ca_CA |
project.funder.name | Consejo Nacional de Investigaciones Científicas y Técnicas (Argentina) | ca_CA |
oaire.awardNumber | 2013/07296–2 | ca_CA |
oaire.awardNumber | 001 | ca_CA |
oaire.awardNumber | UJI-B2022-56 | ca_CA |
oaire.awardNumber | UJI-B2019-30 | ca_CA |
oaire.awardNumber | CIAICO2021/122 | ca_CA |
oaire.awardNumber | UP2021-021 | ca_CA |
oaire.awardNumber | PUE 22920200100016CO-IFIMAR | ca_CA |