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Supramolecular Control of the Oxidative Addition as a Way To Improve the Catalytic Efficiency of Pincer-Rhodium (I) Complexes
dc.contributor.author | Martínez-Vivas, Sebastián | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2023-10-20T06:40:22Z | |
dc.date.available | 2023-10-20T06:40:22Z | |
dc.date.issued | 2023-07-21 | |
dc.identifier.citation | Martínez-Vivas, S., Poyatos, M., Peris, E., Supramolecular Control of the Oxidative Addition as a Way To Improve the Catalytic Efficiency of Pincer-Rhodium (I) Complexes. Angew. Chem. Int. Ed. 2023, 62, e202307198 | ca_CA |
dc.identifier.issn | 1433-7851 | |
dc.identifier.issn | 1521-3773 | |
dc.identifier.uri | http://hdl.handle.net/10234/204607 | |
dc.description.abstract | H-1 NMR studies using a cationic complex with a pyridine-di-imidazolylidene pincer ligand of formula [Rh(CNC)(CO)](+) revealed that this compound showed high binding affinity with coronene in CH2Cl2. The interaction between coronene and the planar Rh-I complex is established by means of & pi;-stacking interactions. This interaction has a strong impact on the electron-donating strength of the pincer CNC ligand, which is increased significantly, as demonstrated by the shifting of the & nu;(CO) stretching bands to lower frequencies. The addition of coronene increases the reaction rate of the nucleophilic attack of methyl iodide on the rhodium (I) pincer complex, and also has a positive effect on the performance of the complex as a catalyst in the cycloisomerization of 4-pentynoic acid. These findings highlight the importance of supramolecular interactions for tuning the reactivity and catalytic activity of square-planar metal complexes. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Angewandte Chemie International Edition, 2023, vol. 62, no 34 | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | ca_CA |
dc.subject | homogeneous catalysis | ca_CA |
dc.subject | oxidative addition | ca_CA |
dc.subject | pincer ligands | ca_CA |
dc.subject | rhodium | ca_CA |
dc.subject | supramolecular chemistry | ca_CA |
dc.title | Supramolecular Control of the Oxidative Addition as a Way To Improve the Catalytic Efficiency of Pincer-Rhodium (I) Complexes | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/anie.202307198 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202307198 | ca_CA |
dc.description.sponsorship | We gratefully acknowledge financial support from the Ministerio de Ciencia e Innovación (PID2021-127862NB-I00), and the Universitat Jaume I (UJI-B2020-01 and UJI-B2021-39). We are grateful to the Serveis Centrals d'Instrumentació Científica (SCIC-UJI) for providing with spectroscopic facilities. | |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Ministerio de Ciencia e Innovación | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
oaire.awardNumber | MCIN/PEICTI2021-2023/PID2021-127862NB-I00 | ca_CA |
oaire.awardNumber | UJI-B2020-01 | ca_CA |
oaire.awardNumber | UJI-B2021-39 | ca_CA |
dc.subject.ods | 3. Salud y bienestar | ca_CA |
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