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A soft-chemistry route to prepare halide perovskite nanocrystals with tunable emission and high optical performance
dc.contributor.author | Silva, Thais Caroline de Almeida | |
dc.contributor.author | Fernández-Saiz, Carolina | |
dc.contributor.author | S. Sánchez, Rafael | |
dc.contributor.author | Gualdrón Reyes, Andrés Fabián | |
dc.contributor.author | Mora-Sero, Ivan | |
dc.contributor.author | Julian-Lopez, Beatriz | |
dc.date.accessioned | 2023-10-18T07:58:02Z | |
dc.date.available | 2023-10-18T07:58:02Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | da Silva, T.C.A., Fernández-Saiz, C., Sánchez, R.S. et al. A soft-chemistry route to prepare halide perovskite nanocrystals with tunable emission and high optical performance. J Sol-Gel Sci Technol (2023). https://doi.org/10.1007/s10971-023-06171-1 | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/204563 | |
dc.description.abstract | Cesium lead halide perovskites constitute a benchmark family of inorganic perovskites for high performance optoelectronic devices. Hot injection is by far the most extended procedure to fabricate CsPbX3 (X: Cl, Br, and/or I) perovskite nanocrystals (PNCs) of high quality. However, the tedious N2-vacuum cycles and fast heating/cooling steps hinder the large-scale production of these materials. This work presents a fast one-step methodology to fabricate small CsPb(ClxBr1-x)3 nanocrystals with good control of the particle size and shape by using a Soft Chemistry strategy (ligand-mediated controlled growth) and microwave heating. We demonstrate that the procedure can be extended to different mixed halide perovskites, thus providing a fine tuning of the chemical composition and consequently, tunable photoluminescence (PL) emission from 522 nm for pure CsPbBr3 to 477 nm for CsPb(Cl0.4Br0.6)3, high photoluminescence quantum yield (PLQY) up to ~86% (for CsPbBr3) and narrow PL full width at half maximum ~18–26 nm. In addition, the protocol was designed in such a way that the chemistry involved in the crystal nucleation and growth of perovskites is as close as possible to that of the hot injection process, which is mechanistically well-understood, to facilitate their adoption by the perovskite research community. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 8 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Springer | ca_CA |
dc.relation.isPartOf | Journal of Sol-Gel Science and Technology, 2023 | ca_CA |
dc.rights | © The Author(s) 2023 | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | ca_CA |
dc.subject | Perovskite nanocrystals | ca_CA |
dc.subject | Emission tuning by halide composition | ca_CA |
dc.subject | Soft-chemistry | ca_CA |
dc.subject | Microwave synthesis | ca_CA |
dc.subject | Optoelectronics | ca_CA |
dc.title | A soft-chemistry route to prepare halide perovskite nanocrystals with tunable emission and high optical performance | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1007/s10971-023-06171-1 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://link.springer.com/article/10.1007/s10971-023-06171-1 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Agencia Estatal de Investigación | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | CRUE-CSIC agreement with Springer Nature | ca_CA |
oaire.awardNumber | MCIN/AEI/10.13039/501100011033/ | ca_CA |
oaire.awardNumber | STABLE PID2019-107314RB-I00 | ca_CA |
oaire.awardNumber | CIPROM/2021/078 | ca_CA |
oaire.awardNumber | UJI-B2021-50 | ca_CA |
oaire.awardNumber | GRISOLIAP/2021/096 | ca_CA |
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