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Nanocomposition of PEDOT:PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaics
dc.contributor.author | Rozhkova, Xeniya | |
dc.contributor.author | Aimukhanov, Aitbek | |
dc.contributor.author | Zeinidenov, Assylbek | |
dc.contributor.author | Paygin, Vladimir | |
dc.contributor.author | Valiev, Damir | |
dc.contributor.author | Bisquert, Juan | |
dc.contributor.author | Guerrero, Antonio | |
dc.contributor.author | Alexeev, Alexander | |
dc.contributor.author | Ilyassov, Baurzhan | |
dc.date.accessioned | 2023-09-13T15:05:03Z | |
dc.date.available | 2023-09-13T15:05:03Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | ROZHKOVA, Xeniya, et al. Nanocomposition of PEDOT: PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaics. Synthetic Metals, 2023, vol. 295, p. 117347 | ca_CA |
dc.identifier.issn | 0379-6779 | |
dc.identifier.issn | 1879-3290 | |
dc.identifier.uri | http://hdl.handle.net/10234/204165 | |
dc.description.abstract | PEDOT:PSS is one of the most widely used materials as a hole selective layer in organic photovoltaics due to its easy processing and high reproducibility. Unfortunately, the material is limited when testing new donor:acceptor systems due to its intrinsic frontier energy levels which typically leads to energy losses due to inadequate energy level alignment and presence of resistive losses. In this work, PEDOT:PSS:metal phthalocyanines nanocomposite thin films are formulated and used as hole transport layer for organic solar cells (OSCs). PEDOT:PSS is formulated with H2Pc, CuPc, CoPc and ZnPc metal phthalocyanines (MPc) with nanobelt morphology which confers the compatibility with the active layer. Atomic force microscopy (AFM) and x-ray diffraction (XRD) were used to study the morphology and structure of nanocomposite films, respectively. OSCs based on PEDOT:PSS:MPc nanocomposite films were fabricated and the effect of hybrid hole transport layer with various phthalocyanines on photovoltaics properties was studied. Overall, nanocomposition of PEDOT:PSS with metal phthalocyanines improves the final power conversion efficiency of solar cells by 20% by a reduction of the resistive losses due to inadequate energy level alignment. The addition of metal phthalocyanines to PEDOT:PSS is a promising method for tailor-made hole transport materials for new donor:acceptor systems to improve their efficiencies. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 10 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Synthetic Metals, 2023, vol. 295, p. 117347 | ca_CA |
dc.rights | © 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/) | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | ca_CA |
dc.subject | polymer solar cells | ca_CA |
dc.subject | PEDOT:PSS | ca_CA |
dc.subject | metal phthalocyanines nanobelts | ca_CA |
dc.subject | I-V characteristics | ca_CA |
dc.subject | impedance spectroscopy | ca_CA |
dc.title | Nanocomposition of PEDOT:PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaics | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1016/j.synthmet.2023.117347 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://www.sciencedirect.com/science/article/pii/S0379677923000693 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Ministry of Education and Science of the Republic of Kazakhstan | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | Ministry of Education and Science (RF MES) | ca_CA |
project.funder.name | Russian Science Foundation | ca_CA |
project.funder.name | Universidad Federal de Kazán | ca_CA |
oaire.awardNumber | AP19174884 | ca_CA |
oaire.awardNumber | UJI-B2020-49 | ca_CA |
oaire.awardNumber | 075-15-2021-710 | ca_CA |
oaire.awardNumber | 19-12-00066-P | ca_CA |
dc.subject.ods | 7. Energia asequible y no contaminante |
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