Effective Ion Mobility and Long-Term Dark Current of Metal Halide Perovskites with Different Crystallinities and Compositions
Impacto
Scholar |
Otros documentos de la autoría: García-Batlle, Marisé; Deumel, Sarah; Tedde, Sandro Francesco; Almora Rodríguez, Osbel; Garcia-Belmonte, Germà
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadatos
Título
Effective Ion Mobility and Long-Term Dark Current of Metal Halide Perovskites with Different Crystallinities and CompositionsAutoría
Fecha de publicación
2022-12Editor
WileyISSN
2699-9293Cita bibliográfica
García-Batlle, M., Deumel, S., Huerdler, J.E., Tedde, S.F., Almora, O. and Garcia-Belmonte, G. (2022), Effective Ion Mobility and Long-Term Dark Current of Metal Halide Perovskites with Different Crystallinities and Compositions. Adv. Photonics Res., 3: 2200136. https://doi.org/10.1002/adpr.202200136Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/adpr.202200136Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Ion transport properties in metal halide perovskite still constitute a subject of intense research because of the evident connection between mobile defects and device performance and operation degradation. In the case ... [+]
Ion transport properties in metal halide perovskite still constitute a subject of intense research because of the evident connection between mobile defects and device performance and operation degradation. In the case of X-ray detectors, dark current level and instability are regarded to be connected to the ion migration upon bias application. Two compositions (MAPbBr3 and MAPbI3) and structures (single- and microcrystalline) are checked by the analysis of long-term dark current evolution. Electronic current increases with time before reaching a steady-state value within a response time (from 104 down to 10 s) that strongly depends on the applied bias. A coupling between electronic transport and ion kinetics exists that ultimately establishes the time scale of electronic current. Effective ion mobility
is extracted for a range of applied electric field ξ. While ion mobility results field-independent in the case of MAPbI3, a clear field enhancement is observed for MAPbBr3 (
), irrespective of the crystallinity. Both perovskite compounds present effective ion mobility in the range of
≈ 10−7–10−6 cm−2 V−1 s−1, in accordance with previous analyses. The ξ-dependence of the ion mobility is related to the lower ionic concentration of the bromide compound. Slower migrating defect drift is suppressed in the case of MAPbBr3, in opposition to that observed here for MAPbI3. [-]
Publicado en
Advanced Photonics Research, 2022, vol. 3, no 12Entidad financiadora
European Commission
Código del proyecto o subvención
info:eu-repo/grantAgreement/EC/H2020/871336
Derechos de acceso
info:eu-repo/semantics/openAccess
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