Re-programming Hydrogel Properties Using a Fuel-Driven Reaction Cycle
![Thumbnail](/xmlui/bitstream/handle/10234/201058/singh_2020_repro.pdf.jpg?sequence=4&isAllowed=y)
Visualitza/
Impacte
![Google Scholar](/xmlui/themes/Mirage2/images/uji/logo_google.png)
![Microsoft Academico](/xmlui/themes/Mirage2/images/uji/logo_microsoft.png)
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONMetadades
Títol
Re-programming Hydrogel Properties Using a Fuel-Driven Reaction CycleAutoria
Data de publicació
2020-03-04Editor
American Chemical SocietyISSN
0002-7863; 1520-5126Cita bibliogràfica
Singh, N., Lainer, B., Formon, G. J., De Piccoli, S., & Hermans, T. M. (2020). Re-programming hydrogel properties using a fuel-driven reaction cycle. Journal of the American Chemical Society, 142(9), 4083-4087.Tipus de document
info:eu-repo/semantics/articleVersió
info:eu-repo/semantics/acceptedVersionParaules clau / Matèries
Resum
Nature uses catalysis as an indispensable tool to control assembly and reaction cycles in vital non-equilibrium supramolecular processes. For instance, enzymatic methionine oxidation regulates actin (dis-)assembly, ... [+]
Nature uses catalysis as an indispensable tool to control assembly and reaction cycles in vital non-equilibrium supramolecular processes. For instance, enzymatic methionine oxidation regulates actin (dis-)assembly, and catalytic guanosine triphosphate hydrolysis is found in tubulin (dis-)assembly. Here we present a completely artificial reaction cycle which is driven by a chemical fuel that is catalytically obtained from a “pre-fuel”. The reaction cycle controls the dis-assembly and re-assembly of a hydrogel, where the rate of pre-fuel turnover dictates the morphology as well as the mechanical properties. By addition of additional fresh aliquots of fuel and removal of waste, the hydrogels can be re-programmed time after time. Overall, we show how catalytic fuel generation can control reaction/assembly kinetics and materials’ properties in life-like non-equilibrium systems. [-]
Publicat a
J. Am. Chem. Soc. 2020, 142, 9, 4083–4087Dades relacionades
https://pubs.acs.org/doi/10.1021/jacs.9b11503Entitat finançadora
Ministère de l’Education Nationale de l’Enseignement supérieur et de la Recherche | French National Research Agency (ANR)
Codi del projecte o subvenció
ERC-2017-STG | 757910 | 17-EURE-0016
Títol del projecte o subvenció
Life-Cycle
Drets d'accés
Copyright © 2020 American Chemical Society
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
Apareix a les col.leccions
- QUIO_Articles [701]