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Pure and Ni2O3-decorated CeO2 nanoparticles applied as CO gas sensor: Experimental and theoretical insights
dc.contributor.author | Amoresi, Rafael | |
dc.contributor.author | Oliveira, Regiane | |
dc.contributor.author | Cichetto Junior, Leonélio | |
dc.contributor.author | Desimone, Paula Mariela | |
dc.contributor.author | Aldao, Celso Manuel | |
dc.contributor.author | Ponce, Miguel Adolfo | |
dc.contributor.author | Gracia, Lourdes | |
dc.contributor.author | Sambrano, Julio | |
dc.contributor.author | Longo, Elson | |
dc.contributor.author | Andres, Juan | |
dc.contributor.author | Simões, Alexandre | |
dc.date.accessioned | 2022-10-24T10:03:56Z | |
dc.date.available | 2022-10-24T10:03:56Z | |
dc.date.issued | 2022-01-29 | |
dc.identifier.citation | AMORESI, Rafael Aparecido Ciola, et al. Pure and Ni2O3-decorated CeO2 nanoparticles applied as CO gas sensor: Experimental and theoretical insights. Ceramics International, 2022, vol. 48, no 10, p. 14014-14025. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/200518 | |
dc.description.abstract | In the present work, the structural, morphological and electrical properties of CeO2 nanoparticles with spherical and rod-like morphologies and rods decorated with Ni2O3 were investigated. Morphological, structural and electronic analyses showed a relationship between the shape/size of particles and the respective surface types, number of carriers, density of vacancies and local structural atomic order, in addition to an influence on the electrical properties of the materials. Electrical analyses revealed that the rod-like morphology has a better CO sensor response than the spherical one. In order to complement and rationalize the experimental findings, simulations at the density functional theory (DFT) were carried out to investigate the two possible mechanisms (Langmuir˗Hinshelwood and Mars-Van Krevelen) acting on the CO adsorption process and elucidate the behavior of the sensor in heterojunction-type samples. | ca_CA |
dc.format.extent | 12 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Ceramics International, 2022, vol. 48, no 10 | ca_CA |
dc.rights | © 2022 Elsevier Ltd and Techna Group S.r.l. All rights reserved. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | ca_CA |
dc.subject | CeO2 | ca_CA |
dc.subject | surfaces | ca_CA |
dc.subject | interfaces | ca_CA |
dc.subject | electrical properties | ca_CA |
dc.title | Pure and Ni2O3-decorated CeO2 nanoparticles applied as CO gas sensor: Experimental and theoretical insights | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1016/j.ceramint.2022.01.286 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Centro de Desenvolvimento de Materiais Funcionais (CDMF) | ca_CA |
project.funder.name | Centros de Pesquisa, Inovação e Difusão (CEPID) | ca_CA |
project.funder.name | São Paulo Research Foundation (FAPESP) | ca_CA |
project.funder.name | National Council for Scientific and Technological Development (CNPq) | ca_CA |
project.funder.name | LNLS - Brazilian Synchrotron Light Laboratory, Research LMF, CNPEM/MCTIC | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | Ministerio de Ciencia, Innovación y Universidades (Spain) | ca_CA |
oaire.awardNumber | 2013/07296-2 | ca_CA |
oaire.awardNumber | 2019/09296-6 | ca_CA |
oaire.awardNumber | 2017/19143-7 | ca_CA |
oaire.awardNumber | 24859 | ca_CA |
oaire.awardNumber | UJI-B2019-30 | ca_CA |
oaire.awardNumber | PGC2018094417-B-I00 | ca_CA |
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