Single-Walled Carbon Nanotubes Encapsulated within Metallacycles
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadata
Title
Single-Walled Carbon Nanotubes Encapsulated within MetallacyclesAuthor (s)
Date
2022-09-26Publisher
WileyISSN
1433-7851; 1521-3773Bibliographic citation
A. López-Moreno, S. Ibáñez, S. Moreno-Da Silva, L. Ruiz-González, N. M. Sabanés, E. Peris, E. M. Pérez, Angew. Chem. Int. Ed. 2022, 61, e202208189; Angew. Chem. 2022, 134, e202208189. https://doi.org/10.1002/anie.202208189Type
info:eu-repo/semantics/articlePublisher version
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202208189Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized ... [+]
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ring-closing metathesis, disulfide exchange reaction, H-bonding or direct threading with macrocycles. Here, we describe the encapsulation of single-walled carbon nanotubes within a palladium-based metallosquare. The formation of MINTs was confirmed by a variety of techniques, including high-resolution transmission electron microscopy. We find the making of these MINTs is remarkably sensitive to structural variations of the metallo-assemblies. When a metallosquare with a cavity of appropriate shape and size is used, the formation of the MINT proceeds successfully by both templated clipping and direct threading. Our studies also show indications on how supramolecular coordination complexes can help expand the potential applications of MINTs. [-]
Is part of
Angewandte Chemie International Edition, 2022, vol. 61, no 35Funder Name
Ministerio de Economía y Competitividad (España) | Ministerio de Ciencia, Innovación y
Universidades | Comunidad de Madrid
Funder ID
http://dx.doi.org/10.13039/501100011033
Project code
MINECO/ICTI2013-2016/CTQ2017-86060-P | MICIU/ICTI2017-2020/PID2020-116661RB-I00 | P2018/NMT-4367 | CEX2020-001039-S
Project title or grant
Novel interfaces between molecules and nanomaterials | Polimeros mecanicamente enlazados con nanotubos de carbono para electrodos de baterías
Rights
info:eu-repo/semantics/openAccess
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- INAM_Articles [523]