Single-Walled Carbon Nanotubes Encapsulated within Metallacycles
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Metadades
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INVESTIGACIONMetadades
Títol
Single-Walled Carbon Nanotubes Encapsulated within MetallacyclesAutoria
Data de publicació
2022-09-26Editor
WileyISSN
1433-7851; 1521-3773Cita bibliogràfica
A. López-Moreno, S. Ibáñez, S. Moreno-Da Silva, L. Ruiz-González, N. M. Sabanés, E. Peris, E. M. Pérez, Angew. Chem. Int. Ed. 2022, 61, e202208189; Angew. Chem. 2022, 134, e202208189. https://doi.org/10.1002/anie.202208189Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202208189Versió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized ... [+]
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ring-closing metathesis, disulfide exchange reaction, H-bonding or direct threading with macrocycles. Here, we describe the encapsulation of single-walled carbon nanotubes within a palladium-based metallosquare. The formation of MINTs was confirmed by a variety of techniques, including high-resolution transmission electron microscopy. We find the making of these MINTs is remarkably sensitive to structural variations of the metallo-assemblies. When a metallosquare with a cavity of appropriate shape and size is used, the formation of the MINT proceeds successfully by both templated clipping and direct threading. Our studies also show indications on how supramolecular coordination complexes can help expand the potential applications of MINTs. [-]
Publicat a
Angewandte Chemie International Edition, 2022, vol. 61, no 35Entitat finançadora
Ministerio de Economía y Competitividad (España) | Ministerio de Ciencia, Innovación y
Universidades | Comunidad de Madrid
Identificador de l'entitat finançadora
http://dx.doi.org/10.13039/501100011033
Codi del projecte o subvenció
MINECO/ICTI2013-2016/CTQ2017-86060-P | MICIU/ICTI2017-2020/PID2020-116661RB-I00 | P2018/NMT-4367 | CEX2020-001039-S
Títol del projecte o subvenció
Novel interfaces between molecules and nanomaterials | Polimeros mecanicamente enlazados con nanotubos de carbono para electrodos de baterías
Drets d'accés
info:eu-repo/semantics/openAccess
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