Single-Walled Carbon Nanotubes Encapsulated within Metallacycles
Impacto
Scholar |
Otros documentos de la autoría: López-Moreno, Alejandro; Ibáñez, Susana; Moreno Da Silva, Sara; Ruiz-González, Luisa; Martín Sabanés, Natalia; Peris, Eduardo; Perez, Emilio
Metadatos
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INVESTIGACIONMetadatos
Título
Single-Walled Carbon Nanotubes Encapsulated within MetallacyclesAutoría
Fecha de publicación
2022-09-26Editor
WileyISSN
1433-7851; 1521-3773Cita bibliográfica
A. López-Moreno, S. Ibáñez, S. Moreno-Da Silva, L. Ruiz-González, N. M. Sabanés, E. Peris, E. M. Pérez, Angew. Chem. Int. Ed. 2022, 61, e202208189; Angew. Chem. 2022, 134, e202208189. https://doi.org/10.1002/anie.202208189Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202208189Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized ... [+]
Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ring-closing metathesis, disulfide exchange reaction, H-bonding or direct threading with macrocycles. Here, we describe the encapsulation of single-walled carbon nanotubes within a palladium-based metallosquare. The formation of MINTs was confirmed by a variety of techniques, including high-resolution transmission electron microscopy. We find the making of these MINTs is remarkably sensitive to structural variations of the metallo-assemblies. When a metallosquare with a cavity of appropriate shape and size is used, the formation of the MINT proceeds successfully by both templated clipping and direct threading. Our studies also show indications on how supramolecular coordination complexes can help expand the potential applications of MINTs. [-]
Publicado en
Angewandte Chemie International Edition, 2022, vol. 61, no 35Entidad financiadora
Ministerio de Economía y Competitividad (España) | Ministerio de Ciencia, Innovación y
Universidades | Comunidad de Madrid
Identificador de la entidad financiadora
http://dx.doi.org/10.13039/501100011033
Código del proyecto o subvención
MINECO/ICTI2013-2016/CTQ2017-86060-P | MICIU/ICTI2017-2020/PID2020-116661RB-I00 | P2018/NMT-4367 | CEX2020-001039-S
Título del proyecto o subvención
Novel interfaces between molecules and nanomaterials | Polimeros mecanicamente enlazados con nanotubos de carbono para electrodos de baterías
Derechos de acceso
info:eu-repo/semantics/openAccess
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- INAM_Articles [517]