Digital video electrochemistry (DVEC) applied to the study of Prussian Blue films
![Thumbnail](/xmlui/bitstream/handle/10234/199659/Roig_ChemElectroChem_2022.pdf.jpg?sequence=4&isAllowed=y)
View/ Open
Impact
![Google Scholar](/xmlui/themes/Mirage2/images/uji/logo_google.png)
![Microsoft Academico](/xmlui/themes/Mirage2/images/uji/logo_microsoft.png)
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
comunitat-uji-handle4:
INVESTIGACIONMetadata
Title
Digital video electrochemistry (DVEC) applied to the study of Prussian Blue filmsAuthor (s)
Date
2022-03-02Publisher
WileyBibliographic citation
GARCÍA‐JAREÑO, José J., et al. Digital video electrochemistry (DVEC) applied to the study of Prussian Blue films. ChemElectroChem, 2022, vol. 9, no 7, p. e202200046.Type
info:eu-repo/semantics/articleVersion
info:eu-repo/semantics/publishedVersionSubject
Abstract
Prussian Blue films were electrogenerated on a Pt disc electrode and color changes were studied by digital video electrochemistry together with cyclic voltammetry. Three systems of peaks were detected. Peaks corresp ... [+]
Prussian Blue films were electrogenerated on a Pt disc electrode and color changes were studied by digital video electrochemistry together with cyclic voltammetry. Three systems of peaks were detected. Peaks corresponding to the reduction to the Everitt's Salt form and to the oxidation to Prussian Yellow are well related to color changes expressed as color intensities derivatives. Color changes showed that these peaks involved complexes mechanisms and intermediate species were detected. These also showed the existence of different sites of iron atoms in the crystal structure with different reactivity. A non-zero baseline and a third electrochemical process at the more negative potentials proved not related to color changes. [-]
Is part of
ChemElectroChem, Volumen 9, Issue 7, April 2022Funder Name
MINECO-FEDER | Excellence Network E3TECH
Project code
CTQ2015-71794-R | CTQ2017-90659-REDT
Rights
© 2022The Authors. ChemElectroChem published by Wiley-VCHGmbH.
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
This item appears in the folowing collection(s)
- QFA_Articles [825]