Mostrar el registro sencillo del ítem
The New Di-Gold Metallotweezer Based on an Alkynylpyridine System
dc.contributor.author | Ibáñez, Susana | |
dc.date.accessioned | 2022-06-20T08:02:27Z | |
dc.date.available | 2022-06-20T08:02:27Z | |
dc.date.issued | 2022-06-02 | |
dc.identifier.citation | Ibáñez, S. The New Di-Gold Metallotweezer Based on an Alkynylpyridine System. Molecules 2022, 27, 3699. https://doi.org/10.3390/molecules27123699 | ca_CA |
dc.identifier.issn | 1420-3049 | |
dc.identifier.uri | http://hdl.handle.net/10234/198080 | |
dc.description.abstract | We developed a simple method to prepare one gold-based metallotweezer with two planar Au-pyrene-NHC arms bound by a 2,6-bis(3-ethynyl-5-tert-butylphenyl)pyridine unit. This metallotweezer is able to bind a series of polycyclic aromatic hydrocarbons through the π-stacking interactions between the polyaromatic guests and the pyrene moieties of the NHC ligands. The metallotweezer was also used as a host for the encapsulation of planar metal complexes, such as the Au(III) complex [Au(C^N^C)(C≡CC6H4-OCH3-p)], for which there is a large binding constant of 946 M−1. | ca_CA |
dc.format.extent | 10 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | MDPI | ca_CA |
dc.relation | Estructuras organometálicas supramoleculares para catálisis y reconocimiento molecular | ca_CA |
dc.relation.isPartOf | Molecules 2022, 27(12), 3699 | ca_CA |
dc.relation.uri | https://www.mdpi.com/article/10.3390/molecules27123699/s1 | |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | ca_CA |
dc.subject | metallotweezer | ca_CA |
dc.subject | gold(I) | ca_CA |
dc.subject | host-guest chemistry | ca_CA |
dc.subject | polycyclic aromatic hydrocarbons (PAHs) | ca_CA |
dc.title | The New Di-Gold Metallotweezer Based on an Alkynylpyridine System | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.3390/molecules27123699 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://www.mdpi.com/1420-3049/27/12/3699 | ca_CA |
dc.description.sponsorship | We gratefully acknowledge financial support from the Ministerio de Ciencia y Universidades (Grant PGC2018-093382-B-I00) and the Universitat Jaume I (Grant UJI-B2020-01). We are grateful to the Serveis Centrals d’Instrumentació Científica (SCIC-UJI) for providing with spectroscopic facilities. | |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.identifier | http://dx.doi.org/10.13039/501100011033 | ca_CA |
project.funder.name | Ministerio de Ciencia, Innovación y Universidades | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
oaire.awardNumber | MICIU/ICTI2017-2020/PGC2018-093382-B-I00 | ca_CA |
oaire.awardNumber | UJI-B2020-01 | ca_CA |
Ficheros en el ítem
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
INAM_Articles [528]