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Redox-active hierarchical assemblies of hybrid polyoxometalate nanostructures at carbon surfaces
dc.contributor.author | Amin, Sharad | |
dc.contributor.author | Cameron, Jamie | |
dc.contributor.author | Cousins, Richard B. | |
dc.contributor.author | Wrigley, James | |
dc.contributor.author | Liirò Peluso, Letizia | |
dc.contributor.author | Sans, Victor | |
dc.contributor.author | Walsh, Darren | |
dc.contributor.author | Newton, Graham | |
dc.date.accessioned | 2022-05-25T10:31:59Z | |
dc.date.available | 2022-05-25T10:31:59Z | |
dc.date.issued | 2022-03-03 | |
dc.identifier.citation | Amin, S. S., Cameron, J. M., Cousins, R. B., Wrigley, J., Liirò-Peluso, L., Sans, V., ... & Newton, G. N. (2022). Redox-active hierarchical assemblies of hybrid polyoxometalate nanostructures at carbon surfaces. Inorganic Chemistry Frontiers, 9(8), 1777-1784. | ca_CA |
dc.identifier.issn | 2052-1553 | |
dc.identifier.uri | http://hdl.handle.net/10234/197809 | |
dc.description.abstract | The self-assembly of hierarchical nanostructures on surfaces is a promising strategy for the development of a wide range of new technologies, such as energy-storage devices and sensors. In this work we show that amphiphilic, organofunctionalized hybrid polyoxometalates spontaneously self-assemble on glassy carbon, graphene oxide, and highly oriented pyrolytic graphite to create hierarchical redox-active nanostructures. The electrochemical behaviour and stability of these supramolecular, nanostructured assemblies is explored in detail and their morphology is determined by comprehensive optical and spectroscopic analyses. The spontaneous assembly of these hybrid nanomaterials on both hydrophilic and hydrophobic carbons is compared and we discuss how this strategy may be a new, simple, and effective method of fabricating hierarchically modified electrode surfaces. | ca_CA |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Inorg. Chem. Front., 2022,9, 1777-1784 | ca_CA |
dc.relation.uri | : Full experimental details and additional cyclic voltammetry, dynamic light scattering, atomic force microscopy, scanning electron microscopy and ellipsometry measurements. See DOI: 10.1039/d2qi00174h | ca_CA |
dc.rights | This journal is © the Partner Organisations 2022 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | ca_CA |
dc.subject | redox-active hierarchical assemblies | ca_CA |
dc.subject | hybrid polyoxometalate nanostructures | ca_CA |
dc.subject | carbon surfaces | ca_CA |
dc.title | Redox-active hierarchical assemblies of hybrid polyoxometalate nanostructures at carbon surfaces | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1039/D2QI00174H | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
project.funder.name | Engineering and Physical Sciences Research Council | ca_CA |
oaire.awardNumber | EP/L015633/1 | ca_CA |
oaire.awardNumber | RPG-2016-442 | ca_CA |
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