Hydration of alkynes catalyzed by Au(III) complexes
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Hydration of alkynes catalyzed by Au(III) complexesAutoría
Tutor/Supervisor; Universidad.Departamento
Mata Martínez, José Antonio; Sancho Llopis, Juan Vicente; Universitat Jaume I. Departament de Química Inorgànica i Orgànica; Universitat Jaume I. Departament de Química Física i AnalíticaFecha de publicación
2020-06-25Editor
Universitat Jaume IResumen
Initially, gold was completely ignored because of its inactivity on homogenous catalysis.
This idea changed over the 2000s, when the homogenous gold catalysts were proven to
be useful to perform different synthesis ... [+]
Initially, gold was completely ignored because of its inactivity on homogenous catalysis.
This idea changed over the 2000s, when the homogenous gold catalysts were proven to
be useful to perform different synthesis reactions, such as the hydration of terminal and
internal alkynes. In these particular reactions, Au(I) and Au(III) complexes are able to
activate the alkynes by nucleophilic attack. The hydration of terminal alkynes is relatively
straightforward since it is only obtained the Markovnikov product, but the hydration of
internal alkynes is slower and not regioselective. In this work we will focus on the activity
and selectivity of Au(III) catalysts. [-]
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Treball Final de Grau en Química. Codi: QU0943. Curs acadèmic: 2019/2020
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