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Shape-Adaptability and Redox-Switching Properties of a Di-Gold Metallotweezer
dc.contributor.author | Ibáñez, Susana | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2021-07-06T07:43:09Z | |
dc.date.available | 2021-07-06T07:43:09Z | |
dc.date.issued | 2021-04-12 | |
dc.identifier.citation | IBÁÑEZ, Susana; PERIS, Eduardo. Shape‐adaptability and redox‐switching properties of a di‐gold metallotweezer. Chem. Eur. J. 2021, 27, 9661-9665. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/193650 | |
dc.description.abstract | The use of a carbazolyl-connected di-gold(I) metallotweezer for the encapsulation of several electron-poor organic substrates, and a planar Au(III) complex containing a CNC pincer ligand, is described. The binding affinity of the receptor depends on the electron-deficient character of the planar guest, with larger association constants found for the more electron-poor guests. The X-ray diffraction molecular structures of two host:guest adducts show that the host approaches its arms in order to facilitate the optimum interaction with the surface of the planar guests, in a clear example of an guest-induced fit conformational arrangement. The electrochemical studies of the encapsulation of N,N’-dimethyl-naphthalenetetracarboxy diimide (NTCDI) show that the redox active guest is released from the receptor upon one electron reduction, thus constituting an example of redox-switchable binding. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 5 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.publisher | Asian Chemical Editorial Society (ACES) | ca_CA |
dc.publisher | ChemPubSoc Europe | ca_CA |
dc.relation.isPartOf | Chem. Eur. J. 2021, 27 | ca_CA |
dc.rights | © 2021 The Authors. Chemistry - A European Journal published by WileyVCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-sa/4.0/ | ca_CA |
dc.subject | gold | ca_CA |
dc.subject | host-guest chemistry | ca_CA |
dc.subject | metallo-tweezers | ca_CA |
dc.subject | redox-switchable binding | ca_CA |
dc.subject | supramolecular | ca_CA |
dc.title | Shape-Adaptability and Redox-Switching Properties of a Di-Gold Metallotweezer | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/chem.202100794 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Ministerio de Ciencia y Universidades, Spain | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
oaire.awardNumber | PGC2018-093382-B-I00 | ca_CA |
oaire.awardNumber | UJI-B2017-07 | ca_CA |
oaire.awardNumber | UJI-B2020-01 | ca_CA |
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Excepto si se señala otra cosa, la licencia del ítem se describe como: © 2021 The Authors. Chemistry - A European Journal published by WileyVCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.