Chemo-enzymatic production of omega-3 monoacylglycerides using sponge-like ionic liquids and supercritical carbon dioxide
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Otros documentos de la autoría: Villa, Rocio; Álvarez, Elena; Nieto Cerón, Susana; Donaire, Antonio; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Lozano, Pedro
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https://doi.org/10.1039/D0GC02033H |
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Chemo-enzymatic production of omega-3 monoacylglycerides using sponge-like ionic liquids and supercritical carbon dioxideAutoría
Fecha de publicación
2020-07-22Editor
Royal Society of ChemistryCita bibliográfica
VILLA, Rocio, et al. Chemo-enzymatic production of omega-3 monoacylglycerides using sponge-like ionic liquids and supercritical carbon dioxide. Green Chemistry, 2020, vol. 22, no 17, p. 5701-5710.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlelanding/2020/gc/d0gc02033h#!divAbstractVersión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
A clean chemo-enzymatic synthesis of omega-3 monoacylglycerides was carried out by two consecutive catalytic steps, the enzymatic transesterification of raw fish or linseed oil with solketal for producing fatty acid ... [+]
A clean chemo-enzymatic synthesis of omega-3 monoacylglycerides was carried out by two consecutive catalytic steps, the enzymatic transesterification of raw fish or linseed oil with solketal for producing fatty acid solketyl esters, followed by the hydrolysis of these solketal moieties catalysed by solid acids (e.g. zeolites) in either supercritical carbon dioxide (scCO2) or sponge-like ionic liquids (SLILs). By using scCO2 as reaction/extraction medium, an excellent performance of both coupled catalytic steps was observed when t-butanol was used as a co-solvent, resulting in a 100% monoacylglyceride yield for seven days under continuous operation and without any loss in catalytic activity. For discontunuous operation, the process involved two separated steps in SLIL and water, respectively, leading to 100% product yield and IL-free monoacylglyceride product by following a cooling and centrifugation protocol, which allow for the full recovery of the enzyme / SLIL / zeolite components of the reaction system that could be reused for at least 6 cycles with unchanged catalytic performance. [-]
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Green Chemistry, 2020, v. 22Proyecto de investigación
1) Partially supported by RTI2018-098233-B-C21; 2) RTI2018-098233-B-C22 (MICINN); 3) PROMETEO/2016/071 (Generalitat Valenciana); 4) 20790/PI/18 (Fundacion SENECA CARM) grants.Derechos de acceso
http://rightsstatements.org/vocab/CNE/1.0/
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info:eu-repo/semantics/restrictedAccess
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