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dc.contributor.authorWeilhard, Andreas
dc.contributor.authorSalzmann, Kevin
dc.contributor.authorNavarro, Miquel
dc.contributor.authorDupont, Jairton
dc.contributor.authoralbrecht, martin
dc.contributor.authorSans, Victor
dc.date.accessioned2020-11-02T08:11:31Z
dc.date.available2020-11-02T08:11:31Z
dc.date.issued2020-03-19
dc.identifier.citationWEILHARD, Andreas, et al. Catalyst design for highly efficient carbon dioxide hydrogenation to formic acid under buffering conditions. Journal of catalysis, 2020, 385: 1-9.ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/190185
dc.description.abstractWe report on new ruthenium complexes as catalysts for the efficient transformation of CO2 into formic acid employing basic ionic liquids as buffering media. Remarkably, these complexes catalyze the hydrogenation of CO2 selectively and without employing strong bases, which improves the sustainability of the process when compared to common base-mediated technologies. The molecular catalyst design relies on donor-flexible and synthetically versatile pyridylidene amide (PYA) ligands which allows the ligand architecture to be varied in a controlled manner to gain valuable insights for the improvement of catalyst performance. Modification of the ligand properties directly influence the catalytic process by shifting the turnover limiting step, the reaction mechanism and the stability upon the acidification of the reaction media and provide access to high-performance systems reaching turnover numbers of several thousands and turnover frequencies up to 350 h−1.ca_CA
dc.format.extent9 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherElsevierca_CA
dc.rights© 2020 Elsevier Inc. All rights reserved.ca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectionic liquidsca_CA
dc.subjectcarbon dioxideca_CA
dc.subjecthydrogenationca_CA
dc.subjectbufferingca_CA
dc.subjectformic acidca_CA
dc.titleCatalyst design for highly efficient carbon dioxide hydrogenation to formic acid under buffering conditionsca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttps://doi.org/10.1016/j.jcat.2020.02.027
dc.relation.projectIDGeneralitat Valenciana (CIDEGENT 2018/36) ; European Research Council (CoG 615653) ; Swiss National Science Foundation (200020_182663)ca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttps://www.sciencedirect.com/science/article/pii/S0021951720300828ca_CA
dc.contributor.funderUniversity of Nottingham, Faculty of Engineeringca_CA
dc.type.versioninfo:eu-repo/semantics/submittedVersionca_CA


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