Mostrar el registro sencillo del ítem
Hexanuclear Niobium Cluster Compounds with Protonated N‐Base Cations
dc.contributor.author | König, Jonas | |
dc.contributor.author | Dartsch, Ina | |
dc.contributor.author | Sperlich, Eric | |
dc.contributor.author | Guillamón, Eva | |
dc.contributor.author | Llusar, Rosa | |
dc.contributor.author | Köckerling, Martin | |
dc.date.accessioned | 2020-10-08T15:13:06Z | |
dc.date.available | 2020-10-08T15:13:06Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | KÖNIG, Jonas, et al. Hexanuclear Niobium Cluster Compounds with Protonated N‐Base Cations. Zeitschrift für anorganische und allgemeine Chemie, 2020 | ca_CA |
dc.identifier.issn | 0044-2313 | |
dc.identifier.issn | 1521-3749 | |
dc.identifier.uri | http://hdl.handle.net/10234/189925 | |
dc.description.abstract | Octahedral clusters of the [M6X12] type offer numerous possibilities to form structural arrangements through different choices of bonding situations. In this paper a series of new cluster compounds of the transition metal niobium is described, which consist of the [Nb6Cl18]2–, and in one case [Nb6Cl18]3–, anion and protonated N‐base cations ([MIm‐H]+, [nPr3N‐H]+, [TMGu‐H]+, and [Tzn‐H]+). They all are prepared using water scavenger compounds [SOCl2 or (Ac)2O] under oxidising conditions, resulting in two‐electron (or one‐electron, respectively) oxidized cluster units with respect to the starting material [Nb6Cl14(H2O)4]·4H2O. Of five members of this group single‐crystal X‐ray structures were determined. The cluster anions exist in all structures as discrete units. The acidic H atoms of all N‐bases are hydrogen bonded to H acceptors, in 4 cases to outer, exo bonded Cl atoms of the cluster unit and in one case to the O atom of a co‐crystallized THF molecule. In [TMGu‐H]2[Nb6Cl18] chains of cluster anions exist hydrogen‐bonded through bridging [TMGu‐H]+ cations. ESI mass spectra of [MIm‐H]2[Nb6Cl18]·2SOCl2 and [TMGu‐H]2[Nb6Cl18] show the expected isotopic distribution patterns for the anions together with other peaks associated to chloride mass losses and/or reduction processes. | ca_CA |
dc.format.extent | 8 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Zeitschrift für anorganische und allgemeine Chemie, 2020 | ca_CA |
dc.rights | © 2020 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | ca_CA |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-sa/4.0/ | * |
dc.subject | cluster | ca_CA |
dc.subject | niobium | ca_CA |
dc.subject | mass spectrometry | ca_CA |
dc.subject | X-ray diffraction | ca_CA |
dc.subject | hydrogen bonds | ca_CA |
dc.title | Hexanuclear Niobium Cluster Compounds with Protonated N‐Base Cations | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/zaac.202000097 | |
dc.relation.projectID | Support from the Deutsche Forschungsgemeinschaft (DFG) through the SPP 1708 is gratefully acknowledged (KO 1616/8). The authors thank Dr. A. Villinger (Universität Rostock) for maintaining the func- tionality of the X-ray facilities. Open access funding enabled and orga- nized by Projekt DEAL. | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://onlinelibrary.wiley.com/doi/full/10.1002/zaac.202000097?af=R | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
Ficheros en el ítem
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
QFA_Articles [826]
Articles de publicacions periòdiques
Excepto si se señala otra cosa, la licencia del ítem se describe como: © 2020 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.