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A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
dc.contributor.author | Ruiz-Botella, Sheila | |
dc.contributor.author | Vidossich, Pietro | |
dc.contributor.author | Ujaque, Gregori | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2020-05-11T10:24:19Z | |
dc.date.available | 2020-05-11T10:24:19Z | |
dc.date.issued | 2020-03-14 | |
dc.identifier.citation | RUIZ-BOTELLA, Sheila; VIDOSSICH, Pietro; UJAQUE, Gregori; PERIS, Eduardo (2020). A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium. Dalton Transactions (2020), issue 10 | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/187930 | |
dc.description.abstract | A tetrabenzoimidazolium-resorcinarene cavitand was used for the preparation of a tetra-benzoimidazolylidene of rhodium, which is unprecedented in the field of poly-NHC metal complexes. Both, the experimental and computational analysis of the molecule reveal a distorted vase conformation as the most stable one, although several non-interconverting conformational isomers due to the restricted rotation about the Rh-C(carbene) bond coexist in the product. There is a fluxional behaviour involving the vase-kite interconversion. The main interactions between the arms of the cavitand are mostly concentrated on the terminal organometallic fragments attached to the NHC, along with those between -CH3 and N-heterocyclic carbene ring from benzoimidazoles. | ca_CA |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Dalton Transactions (2020), Issue 10 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.subject | Tetrabenzoimidazolium-resorcinarene cavitand | ca_CA |
dc.subject | Rhodium | ca_CA |
dc.subject | Poly-NHC metal complexes | ca_CA |
dc.subject | Molecule analysis | ca_CA |
dc.subject | Non-interconverting conformational isomers | ca_CA |
dc.subject | Vase-kite interconversion | ca_CA |
dc.subject | Benzoimidazoles | ca_CA |
dc.title | A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1039/d0dt00060d | |
dc.relation.projectID | 1) Ministerio de Ciencia y Universidades (PGC2018-093382-B-I00); 2) Universitat Jaume I (UJI-B2017-07); 3) Spanish MINECO-FEDER (CTQ2017-87889-P, PGC2018-093382B-I00 and CTQ2016-81797-REDC); 4) Generalitat de Catalunya (2017SGR1323). | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.rsc.org/en/content/articlelanding/2020/dt/d0dt00060d/unauth#!divAbstract | ca_CA |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
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