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Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols
dc.contributor.author | Sorribes, Iván | |
dc.contributor.author | Lemos, Samantha | |
dc.contributor.author | Martín Solans, Santiago | |
dc.contributor.author | Mayoral, Álvaro | |
dc.contributor.author | Lima, Renata C | |
dc.contributor.author | Andres, Juan | |
dc.date.accessioned | 2020-03-31T11:58:28Z | |
dc.date.available | 2020-03-31T11:58:28Z | |
dc.date.issued | 2019-11 | |
dc.identifier.citation | SORRIBES, Iván, et al. Palladium doping of In 2 O 3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols. Catalysis Science & Technology, 2019, vol. 9, no 24, p. 6965-6976. | ca_CA |
dc.identifier.issn | 2044-4753 | |
dc.identifier.issn | 2044-4761 | |
dc.identifier.uri | http://hdl.handle.net/10234/187250 | |
dc.description.abstract | Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C–N bond cleavage methodology is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance. | ca_CA |
dc.format.extent | 12 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Catalysis Science & Technology, 2019, vol. 9, no 24 | ca_CA |
dc.rights | © The Royal Society of Chemistry | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | amides | ca_CA |
dc.subject | amines | ca_CA |
dc.subject | catalysts | ca_CA |
dc.subject | hydrogenation | ca_CA |
dc.subject | palladium | ca_CA |
dc.subject | palladium compounds | ca_CA |
dc.title | Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1039/C9CY02128K | |
dc.relation.projectID | Spanish Ministerio de Ciencia, Innovacion y Universidades: PGC2018-094417-B-I00; Universitat Jaume I: UJI-B2016-25; Spanish Ministerio de Economia, Industria y Competitividad: IJCI-2016-30590; CAPES: 88881.187798/2018-01; CAPES; National Council for Scientific and Technological Development (CNPq); Minas Gerais State Research Foundation (FAPEMIG); Grupo de Materiais Inorganicos do Triangulo (GMIT) - Research Group - FAPEMIG: APQ-00330-14; DGA/fondos FEDER (construyendo Europa desde Aragon): E31_17R SPST of ShanghaiTech University: EM02161943; National Natural Science Foundation of China: NFSC-21850410448, NSFC-21835002 | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.rsc.org/--/content/articlehtml/2019/cy/c9cy02128k | ca_CA |
dc.date.embargoEndDate | 2020-11 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
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