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A Twisted Tetragold Cyclophane from a Fused BisImidazolindiylidene
dc.contributor.author | Gutiérrez-Blanco, Ana | |
dc.contributor.author | Ibáñez, Susana | |
dc.contributor.author | Hahn, Franz Ekkehardt | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2020-03-27T11:17:38Z | |
dc.date.available | 2020-03-27T11:17:38Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | GUTIÉRREZ-BLANCO, Ana, et al. A Twisted Tetragold Cyclophane from a Fused Bis-Imidazolindiylidene. Organometallics, 2019. | ca_CA |
dc.identifier.issn | 0276-7333 | |
dc.identifier.issn | 1520-6041 | |
dc.identifier.uri | http://hdl.handle.net/10234/187172 | |
dc.description.abstract | The reaction between an angular bis-imidazolidinium salt and [AuCl(SMe)2] allowed the preparation of a discrete digold complex, with a rigid angular bridging bis-imidazolindiylidene ligand. This complex reacts with a diethynylcarbazole to afford a tetragold cyclophane that contains two bis-imidazolindiylidenes and two carbazolyl-diethynyl ligands. Both the dimetallic and the tetrametallic complexes have been characterized by spectroscopic techniques and by singlecrystal X-ray diffraction. Due to the geometric constraints of the ligands, the cyclophane deviates from the expected planarity and shows a twisted structure. The work demonstrates that the rigid angular di-NHC ligand is a suitable scaffold for the reliable construction of organometallic-based metallosupramolecular assemblies. | ca_CA |
dc.format.extent | 5 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Organometallics 2019, 38. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.title | A Twisted Tetragold Cyclophane from a Fused BisImidazolindiylidene | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/acs.organomet.9b00719 | |
dc.relation.projectID | PGC2018-093382-BI00 ; (UJI-B2017-07 and UJIA2017-02 | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.acs.org/doi/10.1021/acs.organomet.9b00719 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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