Free ion diffusivity and charge concentration on cross-linked polymeric ionic liquid iongel films based on sulfonated zwitterionic salts and lithium ions
Impacte
Scholar |
Altres documents de l'autoria: Valverde Barquero, David; García Bernabé, Abel; Andrio, Andreu; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Compañ, Vicente
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
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https://doi.org/10.1039/c9cp01903k |
Metadades
Títol
Free ion diffusivity and charge concentration on cross-linked polymeric ionic liquid iongel films based on sulfonated zwitterionic salts and lithium ionsAutoria
Data de publicació
2019Editor
Royal Society of ChemistryISSN
1463-9076; 1463-9084Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://pubs.rsc.org/en/content/articlelanding/2019/cp/c9cp01903k#!divAbstractVersió
info:eu-repo/semantics/publishedVersionResum
The properties of various mixtures of a zwitterionic ionic liquid (ZIs-1) and LiNTf2, including their conductivity, have been studied showing how they can be adjusted through their molar composition. Conductivity tends ... [+]
The properties of various mixtures of a zwitterionic ionic liquid (ZIs-1) and LiNTf2, including their conductivity, have been studied showing how they can be adjusted through their molar composition. Conductivity tends to increase with the LiNTf2 content although it presents a minimum at the region close to the eutectic point. These mixtures also provide excellent features as liquid phases for the preparation of composite materials based on crosslinked PILs. The prepared films display excellent and tuneable properties as conducting materials, with conductivities that can be higher than 10−2 S cm−1 above 100 °C. The selected polymeric compositions show very good mechanical properties and thermal stability, even for low crosslinking degrees, along with a suitable flexibility and good transparency. The final properties of the films correlate with the composition of the monomeric mixture used and with that of the ZIs-1:LiNTf2 mixture. [-]
Publicat a
Phys. Chem. Chem. Phys., 2019, 21, 17923--17932Proyecto de investigación
ENE/2015- 69203-RRTI2018-098233-B-C22
PROMETEO/2016/071
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This journal is © the Owner Societies 2019
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