Molecular relaxation and ionic conductivity of ionic liquids confined in apoly(vinylidenefluoride) polymer matrix: Influence of anion and cation type
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Other documents of the author: Correia, D. M.; Costa, C. M.; Sabater i Serra, Roser; Gómez Tejedor, J. A.; Teruel Biosca, L.; De Zea Bermúdez, Verónica; Esperança, J. M. S. S.; Reis, P. M.; Andrio, Andreu; Meseguer-Dueñas, J. M.; lanceros-mendez, senentxu; Gomez Ribelles, Jose Luis
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/2507
comunitat-uji-handle3:10234/6973
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https://doi.org/10.1016/j.polymer.2019.03.032 |
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Title
Molecular relaxation and ionic conductivity of ionic liquids confined in apoly(vinylidenefluoride) polymer matrix: Influence of anion and cation typeAuthor (s)
Date
2019Publisher
ElsevierISSN
0032-3861Bibliographic citation
CORREIA, D. M., et al. Molecular relaxation and ionic conductivity of ionic liquids confined in a poly (vinylidene fluoride) polymer matrix: Influence of anion and cation type. Polymer, 2019, vol. 171, p. 58-69.Type
info:eu-repo/semantics/bookPublisher version
https://www.sciencedirect.com/science/article/pii/S0032386119302538Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
Blends of poly(vinylidenefluoride) (PVDF) and ionic liquids (ILs) with different cations and anions have beenprepared by solvent casting. The IL content was the same in all blends of the series. Molecular relaxation ... [+]
Blends of poly(vinylidenefluoride) (PVDF) and ionic liquids (ILs) with different cations and anions have beenprepared by solvent casting. The IL content was the same in all blends of the series. Molecular relaxation andionic conductivity have been systematically studied by broadband dielectric relaxation spectroscopy (BDS) inwide frequency (0.1 Hz–1 MHz) and temperature ranges (−120 to 150 °C) and the results have been analysed interms of dielectric modulus M*(ω) and conductivityσ*(ω) formalisms. The main relaxation process (β-relaxa-tion) of the amorphous phase of the blend that integrates amorphous polymer chain segments and IL moleculeswas observed. Significant differences in the Vogel-Fulcher-Tammann (VFT)fitting parameters in the PVDF/ILblends with different anions were detected. The conductivityσ*(ω) formalism shows that it is strongly depen-dent on the miscibility of the IL with the amorphous PVDF chains and the type of anion. The Barton-Namikawa-Nakajima (BNN) relationσ0∼ωcis fulfilled for all PVDF/IL blends except for that containing 1-ethyl-3- me-thylimidazolium hydrogen sulfate, [Emim][HSO4]. The activation energy of theacconductivity, calculatedaccording to the Dyre model, decreases for all PVDF/IL blends with respect to neat PVDF. The structure of thecation of the IL has been found to exert less influence on the dielectric and conductivity properties of the blends. [-]
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Polymer, Volume 171, 2019.Investigation project
UID/FIS/04650/2013 ; PTDC/CTM-ENE/5387/2014 ; PTDC/EEI-SII/5582/2014 ; PTDC/FIS-MAC/28157/2017 ; SFRH/BPD/121526/2016 ; SFRH/BPD/112547/2015 ; IF/00355/2012 ; IF/0621/2015 ; MAT2016-76039-C4-1-R ; MAT2016-76039-C4-3-R ; UID/QUI/50006/2013 ; POCI-01-0145-FEDER-007265 ; PIBA-2018-06Rights
0032-3861/ © 2019 Elsevier Ltd. All rights reserved.
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