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Beige materials for the ceramic industry: AlxVyFe1-xP1-yO4 (0.0 ≤ x ≤ 0.3, 0.0 ≤ y ≤ 0.1) solid solutions
dc.contributor.author | Tena, M. A. | |
dc.date.accessioned | 2019-06-28T07:08:19Z | |
dc.date.available | 2019-06-28T07:08:19Z | |
dc.date.issued | 2019-05 | |
dc.identifier.citation | TENA, M. A., et al. Beige materials for the ceramic industry: AlxVyFe1-xP1-yO4 (0.0≤ x≤ 0.3, 0.0≤ y≤ 0.1) solid solutions. Ceramics International, 2019, vol. 45, no 7, p. 8271-8278. | |
dc.identifier.uri | http://hdl.handle.net/10234/183021 | |
dc.description.abstract | AlxVyFe1-xP1-yO4 (0.0 ≤ x ≤ 0.3, 0.0 ≤ y ≤ 0.1) compositions were synthesized via the chemical co-precipitation method. At 500 °C, α-FePO4 berlinite crystallizes together with FePO4 tridymite, Fe(III) occupying tetrahedral sites in both structures. The variation in the unit cell confirms the formation of solid solutions with α-FePO4 berlinite structure. These AlxVyFe1-xP1-yO4 (0.0 ≤ x ≤ 0.3, 0.0 ≤ y ≤ 0.1) solid solutions are stable between 800 and 1000 °C and when x > 0.2 at 1200 °C. Fe7P6O24 with Fe(II) and Fe(III) is detected in the compositions with the highest amount of Fe(III) at 1200 °C. The materials are paramagnetic between 100 and 300 K and the variation in their magnetic susceptibilities fits the Curie-Weiss law with negative Weiss constants (antiferromagnetism). At 1200 °C, the presence of small amounts of Fe(II) is associated with a slight decrease in μeff. The presence of vanadium in samples (y > 0) decreases their μeff. Optimal beige materials to work without sample fusion at 1200 °C are reported. | ca_CA |
dc.format.extent | 8 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Ceramics International, 2019, vol. 45, no 7 | ca_CA |
dc.rights | Copyright © Elsevier B.V. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | phosphates | ca_CA |
dc.subject | iron | ca_CA |
dc.subject | vanadium | ca_CA |
dc.subject | solid solutions | ca_CA |
dc.subject | magnetism | ca_CA |
dc.title | Beige materials for the ceramic industry: AlxVyFe1-xP1-yO4 (0.0 ≤ x ≤ 0.3, 0.0 ≤ y ≤ 0.1) solid solutions | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | 0272-8842 | |
dc.identifier.doi | https://doi.org/10.1016/j.ceramint.2019.01.133 | |
dc.relation.projectID | Ministerio de Ciencia, Innovación y Universidades: projects MAT2013-40950-R, MAT2016-78155-C2-1-R; ERDF funding | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://www.sciencedirect.com/science/article/pii/S0272884219301634#! | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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