A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap
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Título
A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene TrapFecha de publicación
2019-05-13Editor
WileyISSN
1433-7851; 1521-3773Cita bibliográfica
IBÁÑEZ, Susana; PERIS, Eduardo A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap. Angewandte Chemie International Edition, 2019, vol. 58, no 20, p. 6693-6697Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201902568Versión
info:eu-repo/semantics/acceptedVersionPalabras clave / Materias
Resumen
A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. ... [+]
A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. The cage was used for the recognition of several polycyclic aromatic hydrocarbons. Due to the perfect dimensional match, the supramolecular complex shows a very high affinity for trapping coronene. [-]
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Angewandte Chemie International Edition, 2019, vol. 58, no 20Proyecto de investigación
Universitat Jaume I. Grant Number: UJI-B2017-07 and UJI-A2017-02Derechos de acceso
Copyright © John Wiley & Sons,
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