A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap
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Title
A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene TrapDate
2019-05-13Publisher
WileyISSN
1433-7851; 1521-3773Bibliographic citation
IBÁÑEZ, Susana; PERIS, Eduardo A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap. Angewandte Chemie International Edition, 2019, vol. 58, no 20, p. 6693-6697Type
info:eu-repo/semantics/articlePublisher version
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201902568Version
info:eu-repo/semantics/acceptedVersionSubject
Abstract
A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. ... [+]
A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. The cage was used for the recognition of several polycyclic aromatic hydrocarbons. Due to the perfect dimensional match, the supramolecular complex shows a very high affinity for trapping coronene. [-]
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Angewandte Chemie International Edition, 2019, vol. 58, no 20Investigation project
Universitat Jaume I. Grant Number: UJI-B2017-07 and UJI-A2017-02Rights
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