Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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Título
Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilizationAutoría
Fecha de publicación
2017Editor
De GruyterISSN
0033-4545; 1365-3075Cita bibliográfica
Sokolov, Maxim N., Alexander V. Anyushin, Rita Hernandez-Molina, et al. 2017. Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization. Pure and Applied Chemistry. 89(3): 379-392. Retrieved 23 Jun. 2017, from doi:10.1515/pac-2017-0105Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://www.degruyter.com/view/j/pac.2017.89.issue-3/pac-2017-0105/pac-2017-0105 ...Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of ... [+]
This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed. [-]
Publicado en
Pure and Applied Chemistry, Volume 89, Issue 3 (Mar 2017)Derechos de acceso
info:eu-repo/semantics/openAccess
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