Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization
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comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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Title
Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilizationAuthor (s)
Date
2017Publisher
De GruyterISSN
0033-4545; 1365-3075Bibliographic citation
Sokolov, Maxim N., Alexander V. Anyushin, Rita Hernandez-Molina, et al. 2017. Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization. Pure and Applied Chemistry. 89(3): 379-392. Retrieved 23 Jun. 2017, from doi:10.1515/pac-2017-0105Type
info:eu-repo/semantics/articlePublisher version
https://www.degruyter.com/view/j/pac.2017.89.issue-3/pac-2017-0105/pac-2017-0105 ...Version
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Abstract
This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of ... [+]
This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed. [-]
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Pure and Applied Chemistry, Volume 89, Issue 3 (Mar 2017)Rights
info:eu-repo/semantics/openAccess
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