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Development and characterization of unmodified kaolinite/EVOH nanocomposites by melt compounding
dc.contributor.author | Cabedo, Luis | |
dc.contributor.author | Villanueva Redón, María del Pilar | |
dc.contributor.author | LAGARON, Jose | |
dc.contributor.author | Giménez Torres, Enrique | |
dc.date.accessioned | 2017-03-01T14:02:08Z | |
dc.date.available | 2017-03-01T14:02:08Z | |
dc.date.issued | 2016-10 | |
dc.identifier.citation | CABEDO, Luis, et al. Development and characterization of unmodified kaolinite/EVOH nanocomposites by melt compounding. Applied Clay Science, 2017, vol. 135, p. 300-306. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/166398 | |
dc.description.abstract | Nanocomposites of unmodified kaolinite (Kaol)/ethylene-vinyl alcohol copolymer (EVOH) with different Kaol contents have been obtained by a two-step process: melt blending in an internal mixer and film processing by co-extruding the obtained clay polymer nanocomposites pellets in between two low-density polyethylene (LDPE) layers. The addition of the clay mineral to the molten polymer has been carried out by using a Kaol/EVOH masterbatch containing 15 mass% Kaol. The so-obtained samples have been analysed by means of WAXS, SEM, TEM, DMA and tensile tests. Finally, barrier properties to water vapour and oxygen at two relative humidities have been assessed. Morphological analysis has revealed high degree of dispersion and distribution of the Kaol within the EVOH matrix. A considerable increase in the mechanical and in the barrier properties has been found. The present work puts forward the effectiveness of an unmodified kaolinite for obtaining ultra-high barrier clay mineral/polymer nanocomposites. | ca_CA |
dc.description.sponsorShip | The authors would like to express their gratitude to Ms. Raquel Oliver and Mr. José Ortega for experimental support. The authors acknowledge Mr. Y. Saito, The Nippon Synthetic Chemical Industry Co. Ltd. (NIPPON GOHSEI), Japan, for supplying EVOH; Arciblansa S.A. for supplying the kaolinite. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Applied Clay Science Volume 135, January 2017 | ca_CA |
dc.rights | © 2016 Elsevier B.V. All rights reserved. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | nanocomposites | ca_CA |
dc.subject | kaolinite | ca_CA |
dc.subject | nanocomposite films | ca_CA |
dc.subject | clay minerals | ca_CA |
dc.title | Development and characterization of unmodified kaolinite/EVOH nanocomposites by melt compounding | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1016/j.clay.2016.10.008 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://www.sciencedirect.com/science/article/pii/S0169131716304264 | ca_CA |
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