Tandem Catalysis of an Aldol-'Click' Reaction System within a Molecular Hydrogel
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadata
Title
Tandem Catalysis of an Aldol-'Click' Reaction System within a Molecular HydrogelDate
2016-06Publisher
MDPIBibliographic citation
ARAÚJO, Marco, et al. Tandem Catalysis of an Aldol-‘Click’Reaction System within a Molecular Hydrogel. Molecules, 2016, vol. 21, no 6, p. 744.Type
info:eu-repo/semantics/articlePublisher version
http://www.mdpi.com/1420-3049/21/6/744Subject
Abstract
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent ... [+]
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed. [-]
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Molecules 2016, 21(6)Rights
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info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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