Tandem Catalysis of an Aldol-'Click' Reaction System within a Molecular Hydrogel
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Títol
Tandem Catalysis of an Aldol-'Click' Reaction System within a Molecular HydrogelData de publicació
2016-06Editor
MDPICita bibliogràfica
ARAÚJO, Marco, et al. Tandem Catalysis of an Aldol-‘Click’Reaction System within a Molecular Hydrogel. Molecules, 2016, vol. 21, no 6, p. 744.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://www.mdpi.com/1420-3049/21/6/744Paraules clau / Matèries
Resum
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent ... [+]
A heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed. [-]
Publicat a
Molecules 2016, 21(6)Drets d'accés
© 1996-2016 MDPI AG (Basel, Switzerland) unless otherwise stated
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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