dc.contributor.author | Rahman, Mohammed M. | |
dc.contributor.author | Marwani, Hadi M. | |
dc.contributor.author | Alshehri, Abdelmohsen A. | |
dc.contributor.author | Albar, Hassan A. | |
dc.contributor.author | Bisquert, Juan | |
dc.contributor.author | Asiri, Abdullah M. | |
dc.date.accessioned | 2016-07-22T09:02:45Z | |
dc.date.available | 2016-07-22T09:02:45Z | |
dc.date.issued | 2016-06 | |
dc.identifier.citation | Rahman, Mohammed M., et al. "Room temperature stable ClPrNTf 2 ionic liquid utilizing for chemical sensor development." Journal of Organometallic Chemistry 811 (2016): 74-80. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/161862 | |
dc.description.abstract | A stable ionic liquid was prepared at room-temperature using the metathesis reaction, which was consummated by the reaction of l-Phenylalanine ethyl ester hydrochloride (chlorpromazine hydrochloride) with lithium-bis(trifluoromethane)sulfonamide in water (shortly, ClPrNTf2). The prepared ClPrNTf2 was characterized in details with various conventional methods. Here, a thin-layer of ClPrNTf2 onto glassy carbon electrode (GCE; Surface area: 0.0316 cm2) is deposited with conducting coating agents (5% nafion) to fabricate a selective and selective 3-methoxy phenol sensor in short response time in phosphate buffer solution. The fabricated phenolic chemical sensor is also exhibited higher sensitivity, large-dynamic concentration ranges, long-term stability, and improved electrochemical performances towards 3-methoxy phenol. The calibration plot is linear (r2 = 0.9836) over the large 3-methoxy phenol concentration ranges (0.09 nM to 0.9 mM). The sensitivity and detection limit is ∼2.3244 μAcm−2μM−1 and ∼0.022 ± 0.002 nM (signal-to-noise ratio, at a SNR of 3) respectively. This novel effort is initiated a well-organize way of efficient sensor improvement with ClPrNTf2 ionic liquid for toxic pollutants in environmental and health-care fields in large scales. | ca_CA |
dc.description.sponsorShip | This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, under grant No HiCi/2-130-36. The authors, therefore, acknowledge with thanks DSR for technical and financial support. | ca_CA |
dc.format.extent | 16 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.relation.isPartOf | Journal of Organometallic Chemistry Volume 811, 1 June 2016 | ca_CA |
dc.rights | Copyright © 2016 Elsevier B.V. or its licensors or contributors. ScienceDirect ® is a registered trademark of Elsevier B.V. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | ClPrNTf2 ionic liquid | ca_CA |
dc.subject | 3-Methoxy phenol | ca_CA |
dc.subject | Glassy carbon electrode | ca_CA |
dc.subject | Sensitivity | ca_CA |
dc.subject | I-V method | ca_CA |
dc.title | Room temperature stable ClPrNTf2 ionic liquid utilizing for chemical sensor development | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1016/j.jorganchem.2016.03.014 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://www.sciencedirect.com/science/article/pii/S0022328X16300894 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | |