• openAccess   A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap 

      Ibáñez, Susana; Peris, Eduardo Wiley (2019-05-13)
      A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. ...
    • openAccess   A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes 

      Martínez Agramunt, Víctor; Eder, Tobias; Darmandeh, Heidar; Guisado-Barrios, Gregorio; Peris, Eduardo Wiley (2019-04-19)
      A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the ...