ListarINAM_Articles por tema "homogeneous catalysis"
Mostrando ítems 1-5 de 5
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A Redox-Switchable Gold(I) Complex for the Hydroamination of Acetylenes: A Convenient Way for Studying Ligand-Derived Electronic Effects
American Chemical Society (2022-03-31)A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC) ligand was prepared and characterized. The electrochemical studies reveal that the complex is able to undergo two successive reduction ... -
A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
Wiley (2023-05-12)The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially ... -
Efficient carbon dioxide hydrogenation to formic acid with buffering ionic liquids
Springer Nature (2021-01-11)The efficient transformation of CO2 into chemicals and fuels is a key challenge for the decarbonisation of the synthetic production chain. Formic acid (FA) represents the first product of CO2 hydrogenation and can be a ... -
Redox-Switchable Cycloisomerization of Alkynoic Acids with Napthalenediimide-Derived N-Heterocyclic Carbene Complexes
Wiley (2021-09-01)Two naphthalene-diimide (NDI) bis-imidazolium salts have been used as N-heterocyclic carbene (NHC) precursors for the preparation of NDI-functionalized complexes of rhodium and iridium of general formula [MCl(NDI-NHC)(COD)] ... -
Supramolecular Control of the Oxidative Addition as a Way To Improve the Catalytic Efficiency of Pincer-Rhodium (I) Complexes
Wiley (2023-07-21)H-1 NMR studies using a cationic complex with a pyridine-di-imidazolylidene pincer ligand of formula [Rh(CNC)(CO)](+) revealed that this compound showed high binding affinity with coronene in CH2Cl2. The interaction between ...