Listar INAM_Articles por título
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Redox-Switchable Cycloisomerization of Alkynoic Acids with Napthalenediimide-Derived N-Heterocyclic Carbene Complexes
Wiley (2021-09-01)Two naphthalene-diimide (NDI) bis-imidazolium salts have been used as N-heterocyclic carbene (NHC) precursors for the preparation of NDI-functionalized complexes of rhodium and iridium of general formula [MCl(NDI-NHC)(COD)] ... -
Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles
Wiley (2020-08-17)We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid organic–inorganic polyoxometalates (POMs). The covalent attachment ...
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Reduced Graphene Oxides as Carbocatalysts in Acceptorless Dehydrogenation of N-Heterocycles
American Chemical Society (2021-11-22)The catalytic properties of graphene-derived materials are evaluated in acceptorless dehydrogenation of N-heterocycles. Among them, reduced graphene oxides (rGOs) are active (quantitative yields in 23 h) under mild conditions ...
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Relative Impacts of Methylammonium Lead Triiodide Perovskite Solar Cells Based on Life Cycle Assessment
Elsevier (2017-11-22)The environmental performance of four different device assembly procedures based on hybrid halide perovskite solar cell (PSC) were assessed from cradle to grave using life cycle assessment (LCA) methodology. In addition, ...
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Removing Instability-Caused Low-Frequency Features in Small Perturbation Spectra of Perovskite Solar Cells
American Chemical Society (2020-06-29)Small-perturbation frequency-domain techniques such as impedance spectroscopy and intensity-modulated photocurrent spectroscopy (IMPS) have become important methods for the investigation of the physical working mechanisms ...
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Resistance transient dynamics in switchable perovskite memristors
AIP Publishing (2023-09)Memristor devices have been investigated for their properties of resistive modulation that can be used in data storage and brain-like computation elements as artificial synapses and neurons. Memristors are characterized ...
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Revealing giant exciton fine-structure splitting in two-dimensional perovskites using van der Waals passivation
ACS Publications (2022-09-08)Organic–inorganic layered perovskites are currently some of the most promising 2D van der Waals materials. Low crystal quality usually broadens the exciton line width, obscuring the fine structure of the exciton in ...
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Revealing the contribution of singlet oxygen in the photoelectrochemical oxidation of benzyl alcohol
Royal Society of Chemistry (2021-02)Photoelectrochemical approaches are finding use in the transformation of organic molecules beyond water oxidation and CO2 reduction. Among the different reactions that can be performed, the selective oxidation of alcohols ...
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Reversible Formation of Gold Halides in Single‐Crystal Hybrid‐Perovskite/Au Interface upon Biasing and Effect on Electronic Carrier Injection
Wiley (2019-08-08)Solar cells, light emitting diodes, and X‐ray detectors based on perovskite materials often incorporate gold electrodes, either in direct or indirect contact with the perovskite compound. Chemical interactions between ...
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Role of Metal Contacts on Halide Perovskite Memristors
Wiley (2023-10-16)Halide perovskites are promising candidates for resistive memories (memristors) due to their mixed electronic/ionic conductivity and the real activation mechanism is currently under debate. In order to unveil the role of ...
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Role of Pd in the Electrochemical Hydrogenation of Nitrobenzene Using CuPd Electrodes
Wiley (2022-04)Interest in the electrochemical reduction of organic compounds as an alternative to hydrogen electrosynthesis is driven, among other reasons, by the fact that the products obtained in this process may have more economic ... -
Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion
Elsevier (2018)The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)] (CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH (CO)2(CTRZNCTRZ)] was ...
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Secondary Amine Catalysis in Enzyme Design: Broadening Protein Template Diversity through Genetic Code Expansion
Wiley (2024)Secondary amines, due to their reactivity, can transform protein templates into catalytically active entities, accelerating the development of artificial enzymes. However, existing methods, predominantly reliant on modified ...
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Selective conversion of various monosaccharaides into sugar acids by additive‐free dehydrogenation in water
Wiley (2020)Abundant sugars of five and six carbon atoms are promising candidates for the production of valuable platform chemicals. Here, we describe the catalytic dehydrogenation of several pentoses and hexoses into their corresponding ...
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Selective Growth of Layered Perovskites for Stable and Efficient Photovoltaics
Royal Society of Chemistry (2018-11)Perovskite solar cells (PSCs) are promising alternatives toward clean energy because of their high-power conversion efficiency (PCE) and low materials and processing cost. However, their poor stability under operation ...
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Self-Assembly of Di-N-Heterocyclic Carbene-Gold-Adorned Corannulenes on C60
Wiley (2017-08-04)The deprotonation of a corannulene-based bisazolium salt allowed the preparation of a corannulene-based NHC di-AuI complex. The prepared di-AuI-complex was tested in the recognition of fullerene-C60, demonstrating good ...
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Self-supported ultra-active NiO-based electrocatalysts for the oxygen evolution reaction by solution combustion
Royal Society of Chemistry (2021-04-20)The oxygen evolution reaction (OER) is a fundamental process to develop a technology that can drive energy transition towards renewable and sustainable fuels. Nevertheless, efficient and straightforward methodologies to ...
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Semiconductor α‐Fe2O3 Hematite Fabricated Electrode for Sensitive Detection of Phenolic Pollutants
Wiley (2018-11-23)Hematite (α‐Fe2O3) semiconductor is an abundant and non‐toxic catalyst for different (photo)electrochemical reactions. In this work, a selective p‐nitrophenol sensor was developed by fabricating a thin‐layer of a glassy ...
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Separating bulk and surface processes in NiOx electrocatalysts for water oxidation
Royal Society of Chemistry (2020-08-10)Nickel oxide-based catalysts currently represent the state of the art in electrochemical water oxidation in alkaline pH. However, much of their functionality remains poorly understood, particularly regarding catalytically ...
