Listar INAM_Articles por autoría "eb337365-e695-4ade-91a6-9e4a5dd95d52"
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Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers
Ibáñez, Susana; Vicent Barrera, Cristian; Peris, Eduardo Wiley (2022-01-10)In this study we report the preparation of a new mechanically interlocked molecule formed by the self-aggregation of two metallotweezers composed by two pyrene-imidazolylidene gold(I) arms and a pyridine-centered pentacyclic ... -
Introducing Ion Mobility Mass Spectrometry to Identify Site-Selective C–H Bond Activation in N-Heterocyclic Carbene Metal Complexes
Mollar Cuni, Andrés; Ibañez-Ibañez, Laura; Guisado-Barrios, Gregorio; Mata Martínez, Jose A; Vicent Barrera, Cristian American Chemical Society (2022-11-14)The activation of C−H bonds in a selective manner still constitutes a major challenge from a synthetic point of view; thus, it remains an active area of fundamental and applied research. Herein, we introduce ion mobility ... -
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
Vicent Barrera, Cristian; Martínez Agramunt, Víctor; Gandhi, Viraj; Larriba, Carlos; Gusev, Dmitry; Peris, Eduardo Wiley (2021)The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry ... -
Ion mobility mass spectrometry uncovers regioselectivity in the carboxylate-assisted C–H activation of palladium N-heterocyclic carbene complexes
Ibañez-Ibañez, Laura; Mollar Cuni, Andrés; Apaloo-Messan , Edmond; Sharma, Akhilesh Kumar; Mata Martínez, Jose A; Maseras, Feliu; Vicent Barrera, Cristian Royal Society of Chemistry (2023-11-27)Carboxylate-assisted Pd-catalyzed C–H bond activation constitutes a mild and versatile synthetic tool to efficiently and selectively cleave inert C–H bonds. Herein, we demonstrate a simple method to experimentally evaluate ... -
Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water
Borja, María Pilar; Vicent Barrera, Cristian; Baya, Miguel; García, Hermenegildo; Mata Martínez, Jose A Royal Society of Chemistry (2018-08-10)We describe an unprecedented catalytic dehydrogenation of glucose by homogeneous catalysts. Iridium ( III ) complexes containing the fragment [Cp*Ir(NHC)] 2+ (NHC = N-heterocyclic carbene ligand) are shown to be very ... -
Selective conversion of various monosaccharaides into sugar acids by additive‐free dehydrogenation in water
Mollar Cuni, Andrés; Byrne, Joseph P.; Borja, María Pilar; Vicent Barrera, Cristian; albrecht, martin; Mata Martínez, Jose A Wiley (2020)Abundant sugars of five and six carbon atoms are promising candidates for the production of valuable platform chemicals. Here, we describe the catalytic dehydrogenation of several pentoses and hexoses into their corresponding ... -
Visible light harvesting alkyne hydrosilylation mediated by pincer platinum complexe
Ibañez-Ibañez, Laura; Lázaro, Ariadna; Mejuto, Carmen; Crespo, Margarita; Vicent Barrera, Cristian; Rodríguez, Laura; Mata Martínez, Jose A Elsevier (2023-12)In this manuscript we assess the catalytic properties of pincer platinum complexes in alkyne hydrosilylation either under photo or thermal conditions. The visible light-induced hydrosilylation proved to be more efficient. ...