ListarInstitute of Advanced Materials (INAM) por tema "ligands"
Mostrando ítems 1-5 de 5
-
An Iron Bis(carbene) Catalyst for Low Overpotential CO2 Electroreduction to CO: Mechanistic Insights from Kinetic Zone Diagrams, Spectroscopy, and Theory
American Chemical Society (2021-12-08)A common challenge in molecular electrocatalysis is the relationship between maximum activity and the overpotential required to reach that rate, with faster catalysts incurring higher overpotentials. This work follows a ... -
Dehydrative coupling of alcohols by Iridium(III) complexes with N-Heterocyclic-Pyridine chelating ligands decorated with Naphthalene-Diimide
American Chemical Society (2023-05-25)A series of dimetallic and monometallic Cp*Ir(III) complexes bearing naphthalene-diimide-decorated N-heterocyclic carbene/pyridine [NDI-(NHC-pyridine)] ligands were prepared and characterized. The complexes show a C,C-chelating ... -
Introducing Ion Mobility Mass Spectrometry to Identify Site-Selective C–H Bond Activation in N-Heterocyclic Carbene Metal Complexes
American Chemical Society (2022-11-14)The activation of C−H bonds in a selective manner still constitutes a major challenge from a synthetic point of view; thus, it remains an active area of fundamental and applied research. Herein, we introduce ion mobility ... -
Ion mobility mass spectrometry uncovers regioselectivity in the carboxylate-assisted C–H activation of palladium N-heterocyclic carbene complexes
Royal Society of Chemistry (2023-11-27)Carboxylate-assisted Pd-catalyzed C–H bond activation constitutes a mild and versatile synthetic tool to efficiently and selectively cleave inert C–H bonds. Herein, we demonstrate a simple method to experimentally evaluate ... -
N-Heterocyclic Carbenes: A Door Open to Supramolecular Organometallic Chemistry
American Chemical Society (2020-07-09)The field of metallosupramolecular chemistry is clearly dominated by the use of O-, N-, and P-donor Werner-type polydentate ligands. These molecular architectures are of high interest because of their wide range of ...