ListarInstitute of Advanced Materials (INAM) por tema "catalysts"
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An Iron Bis(carbene) Catalyst for Low Overpotential CO2 Electroreduction to CO: Mechanistic Insights from Kinetic Zone Diagrams, Spectroscopy, and Theory
American Chemical Society (2021-12-08)A common challenge in molecular electrocatalysis is the relationship between maximum activity and the overpotential required to reach that rate, with faster catalysts incurring higher overpotentials. This work follows a ... -
Dehydrative coupling of alcohols by Iridium(III) complexes with N-Heterocyclic-Pyridine chelating ligands decorated with Naphthalene-Diimide
American Chemical Society (2023-05-25)A series of dimetallic and monometallic Cp*Ir(III) complexes bearing naphthalene-diimide-decorated N-heterocyclic carbene/pyridine [NDI-(NHC-pyridine)] ligands were prepared and characterized. The complexes show a C,C-chelating ... -
Stabilization of Nanoparticles Produced by Hydrogenation of Palladium–N-Heterocyclic Carbene Complexes on the Surface of Graphene and Implications in Catalysis
American Chemical Society (2018)Palladium nanoparticles (NPs) have been obtained by decomposition of well-defined palladium complexes noncovalently anchored onto the surface of reduced graphene oxide. Morphological analysis by microscopy showed the ... -
Strongly Coordinating Ligands To Form Weakly Coordinating Yet Functional Organometallic Anions
American Chemical Society (2019-12-05)Weakly coordinating anions (WCAs) are generally tailored to act as spectators with little or no function. Here we describe the implementation of strongly coordinating dianionic carboranyl N-heterocyclic carbenes (NHCs) to ...