Mostrar el registro sencillo del ítem
Interfacial role of Cesium in Prussian Blue Films
dc.contributor.author | Catalán, R. | |
dc.contributor.author | Agrisuelas, Jerónimo | |
dc.contributor.author | Cuenca, A. | |
dc.contributor.author | García-Jareño, J.J. | |
dc.contributor.author | Roig-Navarro, Antoni F. | |
dc.contributor.author | Vicente, F. | |
dc.date.accessioned | 2015-11-19T13:17:07Z | |
dc.date.available | 2015-11-19T13:17:07Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0013-4651 | |
dc.identifier.issn | 1945-7111 | |
dc.identifier.uri | http://hdl.handle.net/10234/140845 | |
dc.description.abstract | The simultaneous measurement of current, mass, motional resistance and absorbance magnitudes allows the electrochemical cation insertion process to be explained during successive voltammograms around the Prussian Blue ⇄ Everitt's Salt system in CsCl aqueous acid solutions. Two different ways for the entrance of cesium to the porous structure of Prussian Blue have been observed. Firstly, Cs+ is spontaneously absorbed as CsCl into the interstitial cluster of water of the channels formed by the Fe(II)low spinCNFe(III)high spin structural units of the crystal. This chemical absorption involves a spontaneous substitution of inner water molecules of the interstitial water cluster. Finally, Cs+ can act as a counter-ion during electrochemical stabilization process of Prussian Blue by means of successive voltammograms. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | ECS | ca_CA |
dc.relation.isPartOf | Journal of The Electrochemical Society, 162, 9 (2015) | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.subject | electrochemistry | ca_CA |
dc.subject | QCM-R | ca_CA |
dc.subject | motional resistance | ca_CA |
dc.subject | prussian blue | ca_CA |
dc.subject | removal of Cesium | ca_CA |
dc.title | Interfacial role of Cesium in Prussian Blue Films | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1149/2.1061509jes | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://jes.ecsdl.org/content/162/9/H727 | ca_CA |
dc.type.version | info:eu-repo/semantics/acceptedVersion |
Ficheros en el ítem
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
IUPA_Articles [310]