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Synthesis, Structure, Gas-Phase Reactivity, and Catalytic Relevance of Trinuclear Mo3S4 Clusters Bearing Terminal Hydroxo and Hydrosulfido Groups
dc.contributor.author | Beltrán Álvarez, Tomás Francisco | |
dc.contributor.author | Feliz Rodríguez, Marta | |
dc.contributor.author | Llusar, Rosa | |
dc.contributor.author | Safont Villarreal, Vicent Sixte | |
dc.contributor.author | Vicent Barrera, Cristian | |
dc.date.accessioned | 2015-01-15T12:58:31Z | |
dc.date.available | 2015-01-15T12:58:31Z | |
dc.date.issued | 2013-11 | |
dc.identifier.issn | 1099-0682 | |
dc.identifier.uri | http://hdl.handle.net/10234/112460 | |
dc.description.abstract | Molybdenum(IV) hydroxo [Mo3S4(dmpe)3(OH)3]+ (1+) and hydrosulfido [Mo3S4(dmpe)3(SH)3]+ (2+) [dmpe = 1,2-bis(dimethylphosphanyl)ethane] trimetallic cuboidal cluster complexes have been isolated in high yields by treating their chloride precursors with sodium hydroxide or sodium hydrosulfide, respectively. The crystal structures of [1]BPh4 and [2]PF6 confirm that –QH (Q = O, S) groups are coordinated to metal centers. Both hydroxo and hydrosulfido Mo3S4 cluster complexes are fully characterized by spectroscopic, mass spectrometric, and X-ray techniques. A comparative study of the gas-phase dissociation of 1+ and 2+ cations using ESI tandem mass spectrometry is presented, and the results are compared with those already reported for the hydroxo tungsten analogue. The gas-phase reactivity of 1+ and 2+ species towards ethanol and 1-penthanethiol have been explored. The gas-phase-generated [Mo3S4(dmpe)2(O)(OH)]+ cation activates ethanol molecules through a similar mechanism to that proposed for its tungsten congener. The main differences in aldehyde elimination under collision-induced dissociation (CID) conditions between molybdenum and tungsten cluster sulfides are discussed. | ca_CA |
dc.format.extent | 9 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.relation.isPartOf | European Journal of Inorganic Chemistry (2013), 33, p. 5797–5805 | ca_CA |
dc.rights | Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Molybdenum | ca_CA |
dc.subject | Cluster compounds | ca_CA |
dc.subject | Mass spectrometry | ca_CA |
dc.subject | Gas-phase reactions | ca_CA |
dc.subject | Density functional calculations | ca_CA |
dc.title | Synthesis, Structure, Gas-Phase Reactivity, and Catalytic Relevance of Trinuclear Mo3S4 Clusters Bearing Terminal Hydroxo and Hydrosulfido Groups | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/ejic.201300890 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/ejic.201300890/abstract | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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