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First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
dc.contributor.author | Corberán Roc, Rosa | |
dc.contributor.author | Marrot, Sebastien | |
dc.contributor.author | Dellus, Nicolas | |
dc.contributor.author | Merceron-Saffon, Nathalie | |
dc.contributor.author | Kato, Tsuyoshi | |
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | Baceiredo, Antoine | |
dc.date.accessioned | 2014-07-02T12:07:21Z | |
dc.date.available | 2014-07-02T12:07:21Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/10234/96955 | |
dc.description.abstract | Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes have been fully characterized, and their crystal structures have been determined. The two tert-butoxide complexes were tested in the catalytic anti-Markovnikov hydroamination and hydroalkoxylation of acrylonitrile, involving the first catalytic application of a carbodiphosphorane complex reported to date. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Organometallics, 28, 1, p. 326–330 | ca_CA |
dc.rights | Copyright © 2008 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.title | First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O) | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/om8008958 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.acs.org/doi/abs/10.1021/om8008958 | ca_CA |
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